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Enhanced cyclic delocalization and associated energetic, magnetic, structural, and reactivity patterns under an explicitly stated aromaticity criterion.
This is an authored directed relation from the source endpoint to the target endpoint.
Relation ID
chem_heterocycle_to_aromaticity_state_description
Relation type
State / property description state-description
Direction
source → target
Endpoint roles
source: Has state / property description; target: State / property description of
Authored annotation
assigned aromatic or nonaromatic character
Authored explanation
A conjugated heterocycle can be assigned aromatic character using explicit energetic, structural, magnetic, or electronic criteria; heteroatom participation and state can change the assessment.
How to interpret this relation type
The target represents a state, property, observable, or state-dependent description associated with the source system or theory.
source: Has model / approximation; target: Model / approximation of
Authored annotation
represented by cyclic delocalized orbitals
Authored explanation
Molecular-orbital models represent cyclic delocalization associated with aromaticity, but energetic, magnetic, structural, and reactivity criteria need not agree in marginal cases.
How to interpret this relation type
The target is a model, idealization, restricted ansatz, approximation scheme, phenomenological fit, or historical representation used for the source system or theory. It need not have a universal small error parameter and is not thereby a controlled limit or effective theory. The edge label and detail must identify the precise status.
source: Has model / approximation; target: Model / approximation of
Authored annotation
represented by delocalized resonance contributors
Authored explanation
Resonance contributors model aspects of aromatic delocalization, but aromaticity is multidimensional and also assessed through energetic, structural, magnetic, and reactivity criteria.
How to interpret this relation type
The target is a model, idealization, restricted ansatz, approximation scheme, phenomenological fit, or historical representation used for the source system or theory. It need not have a universal small error parameter and is not thereby a controlled limit or effective theory. The edge label and detail must identify the precise status.
Relation sources
Wikipedia — Chemical bond — Chemical bond · encyclopedic reference · source ID wp-physics-chemical-bond
OpenStax — Chemistry 2e — Chemistry 2e · peer-reviewed open textbook · source ID openstax-chemistry-2e