Fields and domains

Relation legend: 25 active meanings

Add data

Equip an existing carrier or structured object with additional chosen data, when such compatible data exists. Use a construction junction when several independently meaningful inputs must coexist on the same carrier or interact compatibly.

Impose axiom

Keep the existing data and select the subclass satisfying an additional law, existence condition, finiteness condition, or other property.

Induced / forgotten

Pass canonically from a stronger object to structure it determines, or forget part of the data while retaining a valid weaker structure. The carrier may change under a canonical induced construction.

Canonical construction

Apply a standard functorial or canonical construction whose output is not merely a reduct of the input and is not generally an equivalent presentation of the same object.

Quotient construction

Identify elements by a stated equivalence relation and equip the quotient with the induced structure. The edge detail must state the representatives and equivalence relation.

Canonical embedding

Map one structure injectively into another by the standard structure-preserving inclusion or representation. This records a canonical copy, not necessarily literal set containment.

Combine compatible structures

Feed several structures into a construction junction and impose compatibility between them.

Representation / equivalence

Reinterpret an object, pass to an equivalent presentation, or relate canonically corresponding structures; the carrier may change.

Theorem implication

Record a genuine theorem implication that is not part of the target definition; these edges may point toward a weaker structure.

Mathematical formulation

A mathematical concept supplies part of the formal language, state space, representation, or analytic machinery used by a scientific or mathematical-physics concept. The source is the mathematical predecessor; this does not claim that physical content follows from mathematics alone.

Framework specialization

A more specific theory, model, entity class, or regime is obtained by restricting or extending the scope of a broader framework.

Quantization

A classical system or field theory is used to construct a quantum theory through a stated quantization procedure. Quantization need not be unique and is not guaranteed to preserve every classical structure.

Theory component

The source supplies a substantive formal ingredient, dynamical sector, law, field content, or mechanism of the target theoretical framework.

Describes / governs

A theory, law, or interaction describes the behavior of the target within a stated regime. The edge detail must state important limits or qualifications.

Physical constitution / realization

The source is a material constituent, structural component, or underlying quantum field whose excitation realizes the target physical system or particle. The edge label and detail must distinguish composition from field excitation; neither implies a simple classical sum of parts.

Classification

The target is a member or subtype of the broader source class.

Physical interaction / binding

The source field, particle, charge, current, or interaction couples to, acts on, binds, forms, or stabilizes the target in the stated regime. The edge label and detail must identify the exact coupling, interaction, or binding claim and its qualifications.

Limit / controlled approximation

The target is recovered from the source either in a stated mathematical or asymptotic limit, or through a quantitatively controlled approximation with identified small parameters or omitted terms. The edge label and detail must state which case applies and its regime of validity.

Effective theory / model

The target retains the degrees of freedom and interactions relevant below a stated scale or within a stated regime, while higher-energy or unresolved degrees of freedom from the source are integrated out, coarse-grained, or encoded in effective couplings.

Model / approximation method

The target is a model, idealization, restricted ansatz, approximation scheme, phenomenological fit, or historical representation used for the source system or theory. It need not have a universal small error parameter and is not thereby a controlled limit or effective theory. The edge label and detail must identify the precise status.

Emergent / collective behavior

The target is a collective, organizational, or scale-dependent phenomenon of the source constituents and interactions; it is not a mere list or classical sum of constituents.

State / property description

The target represents a state, property, observable, or state-dependent description associated with the source system or theory.

Transformation / process

A physical process transforms the source into, or produces, the target under the conditions stated in the edge detail.

Historically motivated

The source experiment, observation, anomaly, or problem materially motivated the development, revision, or acceptance of the target concept. Historical influence is not logical derivation; the edge detail states the documented role and avoids retrospective origin myths.

Experimentally tested / supported by

The source theory, law, entity, prediction, or structural claim is directly tested, supported, constrained, or established by the target experiment or observation. Experimental support is not final logical proof; the edge detail states exactly what was measured.

Browse all 1,330 canonical concepts

These are ordinary HTML links to the canonical concept pages. Construction junctions remain visible in the diagram but are omitted here because they are visual combination devices rather than standalone concepts.

Mathematics

Set theory45

Order theory28

Logic17

Computability theory12

Category theory29

Combinatorics & graph theory18

Universal algebra8

Algebra53

Representation theory14

Number theory35

Algebraic geometry27

Topology36

Algebraic topology21

Differential geometry41

Homological algebra21

Analysis51

Dynamical systems20

Probability15

Measure10

Physics

Physical foundations20

Classical mechanics21

Relativity & gravitation46

Cosmology13

Electromagnetism19

Quantum mechanics61

Thermodynamics & statistical mechanics33

Quantum field theory109

Particle physics96

Nuclear physics51

Atomic & molecular physics70

Condensed-matter physics31

Experiments & observations3

Chemistry

Chemical foundations24

Atomic structure & periodicity18

Molecular structure & bonding21

Quantum chemistry & spectroscopy21

Chemical thermodynamics & equilibrium18

Solutions, acids, bases & interfaces35

Chemical kinetics & dynamics20

Inorganic & coordination chemistry17

Organic chemistry22

Analytical chemistry22

Electrochemistry23

Radiochemistry15

Complete visual graph

Every domain, active relation type, construction junction, and cross-field connection is enabled. Select any concept label in the SVG to open its atlas location.

Atlas of Fundamental ConceptsA source-backed visual atlas connecting mathematics, physics, and fundamental chemistry from formal structures and physical law through chemical composition, bonding, reactivity, measurement, and radiochemical processes. Exported from the current visible graph.Advay MenglemAtlas - Atlas of Fundamental ConceptsmAtlas - Copyright (c) 2026 Advay Mengle - https://atlas.madvay.com/Atlas of Fundamental Conceptshttps://atlas.madvay.com · © 2026 Advay Mengle · CC BY-SA 4.0Exported from the current visible graph; use the atlas site for the latest data and terms.successor stagestransfinite stage indexequip the index setwith two degreecoordinatesequip the index setwith degree indexingforget indices andrepetitionsdegree-indexed objectsordered familydegree-indexed objectstime-indexed variables+ initiality+ membershipwell-orders the setstrictly larger than itsbasechosen as zerorequire ordinal formfinite ordinalssuccessor ordinalslimit ordinalscollect all finiteordinalsfirst limit ordinalfirst infinite ordinalstandard carrier of ℕdefine transfiniteoperationswell-founded recursioncountable ordinalscollect all countableordinalsfirst uncountableordinalleast fixed point of𝜔^(𝛼)distinguishedcountable ordinalcollect as a properclassfinite cardinalsinfinite cardinalsview by cardinalityleast infinite cardinalleast membertake least largercardinallimit cardinalstransfinite successorenumerationsuccessor stageslimit stagesstart at ℶ₀power-set successorstagesstrict growth atsuccessorsfirst power-set step|℘(ℕ)|=𝔠𝔠=ℵ₁specialize to ℵ₀ℶ_(𝛼)=ℵ_(𝛼)+ strong cardinalpropertyinaccessible cardinalsmeasurable cardinalssupercompactcardinalsmeasurable impliesinaccessiblesupercompact impliesmeasurableno greatest ordinalfunctionals andvariationsread domain as indexsetprojection mapprojection mapunderlying functionbasepoint+ target set 𝑌 and 𝑅⊆𝑋× 𝑌+ countabilityadd vertices, arrows,source, target+ finite cardinalitychoose symbols andarities+ family of subsetsobject setsupply carrieracted-on carriercarrier set+ binary operation+ independencesystem+ 𝜎-algebra+ choose 𝑥₀+ pseudometric 𝑑+ zero and successor+ topology 𝜏+ transitivity+ edges+ uniformityrequire no elementsform all subsetsapply successor𝑆(0)=1iterate from zero+ axiom of choicecontains ACequivalent over ZFcardinal representativefor every setall set cardinalities arealephsequivalent over ZFproves existence anduniquenesspower-set axiomwell-orderablecontinuumwell-order power-setsizesunderlying functionunderlying functionidentify domain andcodomainchoose ordered sourceand targetpair with an orderadjointspecifies identifiedpoints+ reflexive, symmetric,transitive+ total andsingle-valuedadd propositionalvaluation+ reflexive, transitive+ well-foundednessrequire completenessadd modal operator+ complements exist+ relativepseudocomplementsexistforget meet and joinoperationssupply boundsforget Booleanoperationshas top and bottom+ infinite distributivityrequire a least elementsupply distributivityretain finite Heytingoperationstake opposite categoryviewpointsame lattice carriesbothsame order supportsbothimpose compatibilityrequire field-ordercompatibilityrequire translationinvariancerequire ordered-ringlawsimpose compatibilitysupply join structure+ least and greatestelementsrequire arbitrary meetsand joinsimpose distributivitylattice orderlattice orderforget meetsforget joinssupply meet structure+ real closednessrequire least andgreatest elements+ directed supremarequire binary joinsrequire binary meets+ totalityrequire common upperboundsadd persistentvaluation+ antisymmetryview as a thin categorysupply total ordersupply total ordersupply total orderrequire least elementstake ordinal order typeinterpret a formulasuppliesmodel-by-model truthoperation symbols onlychoose a set ofsentencessupply signaturecandidate structurespecialize to analgebraic signaturetheoryinterpret every symbolimpose satisfactionZF theoryZFC theoryspecify effectivederivationsexclude contradictionsdecide every sentencesyntacticallychoose an effectivearithmetical codingenumerate its formaltheoremseffective formal theorythe same theory isconsistentapply Gödel’s theoremeffective formal theorythe same theory isconsistentapply Gödel’s theoremformalize mathematicstake semantic closurefirst-order syntax andsemanticssyntactic consistencyapply Gödelcompletenessfinite proofs yieldcompactnessencode instancescomputablymembership-preservingtranslatorformalizes as aTuring-machineprocedurehas a total decidercomputes a partialfunctionrecognizes orenumerates a setencode and simulatemachinesposes termination ofencoded simulationshas the haltingproblem as a canonicalexamplecorresponds to acomputableinput–output mapunder theChurch–Turing thesismotivated a preciseaccount of effectiveprocedurehas undecidableinstances as a subclasshas a computablyenumerableyes-languagearithmetized syntaxarithmetized syntaxrepresented by anobjectform a hom presheafform 𝐷(𝐴)take all short exactsequences+ AB5 and generatorrequire exactkernel/cokernelbehavior+ conflations+ shift anddistinguished trianglesimpose symmetryadd exponentialssupply exponentialsadd finite products+ dagger involutionrequire finite limitsrequire invertiblearrowsambient categoryambient category+ weak equivalences,fibrations, cofibrationsadd tensor and unitadd abelianhom-groups+ set-sized objects andarrowsat most one arrowinduce internal homsspecialize enrichmentto chain complexesretain finite productssupply finite limitsretainelementary-toposstructurecategorical invertibilityimpose cosimplicialidentitiesadd subobjectclassifier+ enriched homs andcompositionimpose simplicialidentitiesadd braiding+ internal homsenriching monoidalcategoryadd finite biproductspresheaf dataspecialize the target toSetform the sheaf toposcovering structureforget identities andcomposition to aquiverchoose a Set-valuedcontravariant functor+ Grothendieckcovering structurechoose duals andduality mapsmap categoriesstructure-preservinglycompare parallelfunctorspair with an adjointfunctorcontravariantSet-valued functortake a limit of adiagramtake a colimit of adiagramproduct is left adjointto exponentiationretains its finite limitsretains finite productsas limitscompared byadjacency-preservingbijectionscompared byincidence-preservingbijectionstake reflexivereachability+ acyclicityexactly one arrow perpair+ connectedness+ path-connectedvertices+ every possible edgechoose a proper vertexcoloring+ acyclicity+ downward closureand finiteness+ orientation signs+ bipartiteness+ acyclicity+ planar embeddability+ no loops or parallels+ weightsspecialize vertices andedges as atoms andbondsadmitsoperation-compatibleidentificationsquotient by acongruenceensures operationsdescendoperation signatureinterpret everyoperation symbolrequire an identity+ idempotencehas absorbing additivesubgroupsidentify elementsmodulo an idealsupplies thecongruencesatisfies primalityforget additiveinversesadditive carrier 𝑀additive carrier 𝑉affine spacetimestructure+ associativityform the Cliffordalgebraassociativemultiplication+ involutionrequire a unitrequire an antipodegamma-matrix algebrachoose a matrixrepresentationspin double covercoalgebra structureuse as additionSpec, contravariantly+ DCC on idealsrequire nonzeroinversesexclude zero divisors+ unique maximal ideal+ ACC on idealsstate spaces andamplitudesantisymmetric exteriorproduct+ all polynomial rootsforget inversionpropertyforget commutativityas a requirementrequire finite carrier+ global arithmeticformsupply fieldfield structurebase fieldscalar field 𝐹+ finite degree over ℚ+ separabilityadd valuationClifford matricesanticommuting fieldvariables+ commutativityview as a one-objectgroupoidacting groupacting groupgroup lawgroup lawsupply groupgroup structureimpose compatibility+ scalar action+ distributivity,absorbing 0+ scalar multiplicationinfinitesimal gaugealgebraacting Lie algebrainfinitesimalgenerators+ unique left/rightdivision+ bijective translationsand self-distributivity+ associativity+ commutativity+ inversesmultiplicationuse as multiplicationmonoid lawview as a one-objectcategory+ 𝑎𝑏=𝑏𝑎+ nonzero inversesscalar ring 𝑅supply ringring structuresemigroup lawrequire an identity+ additive inversessymmetry-adapteddeterminantcombinationsupplies asingle-configurationfermion ansatzinvolutioncomposite-systemstate space+ commutativityunital algebrastructureforget the chosenorigin+ bilinearmultiplication+ comultiplication andcounitcomplex scalarslinear dualexterior algebrasame algebra;Grassmannterminology+ inner productlinear carrierlinear carriervector structureadd Lie bracketchoose a linearendomorphism+ real-valued absolutevalue and seminormsymplectic formtensor productlinear combinationsindexed direct sumgraded direct-sumstructurecanonical operatorbracketcanonicalanticommutationalgebrainitial arithmeticsemiringprime ordered fieldinvert a multiplicativesubsetform Spec(𝑅)adjoin anindeterminatespecify a larger fieldrequire algebraicelementsrequire separabilityrequire normalitychoose polynomialsand adjoin all rootsis a normal algebraicextensiontake invertible fieldmapstake base-fixingautomorphismsrealized by fieldsymmetriestake common fixedelementssubgroups correspondto subfieldslocal isotropy decidesglobal isotropyis separableis normalis a commutative ringnormal extensionseparable extensionimpose both propertieson one extensionis a vector space overthe base fieldis a subfieldis a groupits Galois groupthe same group issolvableapply the Galoiscriterionchosen polynomial andsplitting fieldtake the projectivezero locus underregularity hypotheses+ projective liftingproperty+ injective extensionpropertytakes matrix tracesyields an irreduciblecharacter𝑈(1)_(𝑌) factorchanges to the coupledangular-momentumbasischanges to the coupledangular-momentumbasisfix the acting group 𝐺tensor-productdecompositionsymmetryrepresentationirreducibilityunitarityone-particle symmetryrepresentationimpose compatibilityimpose compatibilityimpose compatibility𝑠𝑢(2) generatorsLorentz group actionform translationssemidirect LorentztransformationsPoincaré group actionflat-spacetimesymmetry𝑆𝑈(2)_(𝐿) and𝑆𝑈(3)_(𝐶) factorsnon-Abelian gaugegroupschoose a spinrepresentationspinor representationLorentz spinortransformationsymmetryrepresentationcharacter of thelattice-translationgroupsymmetry operationsact on molecularcoordinatessupply points ofSpec(𝑅)is a PIDrequire atomicfactorizationNoetherian + normal +dimension 1+ Euclidean algorithmrequire gcds+ total divisibility offractions+ characteristic 0,residue characteristic𝑝take integral closure ofrequire local discretevaluation formis a Dedekind domainrequire principal idealscanonically localrequire valuationcompletenessstandard Peano systemform formal differencesidentify equaldifferences𝑛↦[(𝑛,0)]forget thedistinguished integerrealizationforget orderformnonzero-denominatorfractionsidentify equal fractions𝑧↦ 𝑧/1forget thedistinguished rationalrealizationform Dedekind cutsform Cauchysequencesconstant cut / constantsequencecardinality ℵ₀countably infinitecountably infinitecomplete in thevaluation topologyyields a completevalued fieldtake nonnegativeelementsconsider its placescomplete at the placenon-Archimedean finiteextensionchoose an effectivecoding of syntaxrestricted product ofcompletionsvalid for quadraticformsretains the chosenvaluationis a fieldis a topological ringlocal completionchoose a point afterbase changeretain a solution at oneplacealso require no globalrational pointsufficient arithmeticsufficient arithmetic+ Peano axiomschoose source, target,and local sheaf mapimplies Noetherianimpose compatibilityimpose compatibility+ unique compatiblegluingimpose compatibility+ 𝑚-adic completenesslocal structure+ affine open coverfinite ideal condition+ irreducibility andnonemptiness+ local stalks+ globally affinegeometric object+ local Noetherianityand quasi-compactness+ reduced local ringsrequire localNoetherian regularity+ base and structuremorphism+ closed diagonal+ projectivity+ representablediagonal and existenceof étale cover+ group structures+ ring structuresstructure sheaflocalize at a primeis an affine schemetake germs at a pointtake the ring of germsat a pointis canonically thecorresponding affinestalkquotient by themaximal idealembed globally intoevery completionhas local-ring stalksglobal varietyretains the Zariskitopologyrequire a point overevery completionspecialize to a smoothprojective degree-twohypersurfacehas a rational pointexactly when it has alllocal pointsidentify points and usethe final topologyidentifyhomotopy-equivalentspacesis completeis separablecompactnesscompactnesslocally trivialprojection+ linear fibersHausdorff propertyHausdorff propertyHausdorff property+ complete regularitysame topologysame topologyimpose local trivialityimpose local trivialitysame topologysame topology+ continuous fieldoperations+ continuityimpose compatibility+ continuous + and ·impose compatibilitytopological carrierlocal compactnesslocal Euclidean charts+ completenessis first-countableis Hausdorffmetric topology+ countable dense setinduce metric topologyinduce metricuniformity+ point separationimplies first-countablecountable base+ 𝑇₁+ disjointneighborhoods+ normal separation+ regular separationtopological scalarslocally compactHausdorff, nondiscretetopological-group inputlocal-compactnessinputstructure groupadd holomorphic atlasadd smooth atlasforget strictassociativity/unitforget the identitygenerate the Borel𝜎-algebra+ compactness+ compact-generation+ connectednessrequire a contraction+ cell decomposition+ countable localbasestotal and basetopologiestotal, base, and fibertopologiestopologyunderlying spacetopologytopologytopologytopologytopologytopology on 𝑉+ local compactness+ connected localbases+ Euclideanneighborhoods+ smooth half-spacemanifold structure+ paths betweenpoints+ separable completemetrizability+ countable base+ 𝑇₀+ distinguishedsubspace+ singletoncomponents+ clopen basisinduce topologydeform mapscontinuouslytake singular simplicesdomain and codomaintopologiesimpose inverse-imagecontinuity+ continuous inversesupplies theequivalence criterionimplies path-connectedimpose compatibilityimplies connectedness+ contract every loop+ multiplication up tounit homotopyis witnessed byhomotopiesform based loopstake path componentsclassifies connectedcoverings understandard hypothesesiterate loops or mapspherescycles moduloboundariesdualize withcoefficientscocycles modulocoboundariescollect all degrees andadd the cup producttake relative homologyor cohomologyinduces isomorphismsinduces isomorphismstake geometricrealizationis an abelian groupis an abelian grouphas an underlyinggraded objectis a groupis abelian for 𝑛≥2definecoordinate-independentdifferentiationsupplies thedifferentialcovariantdifferentiation𝑈(1)𝑆𝑈(𝑛)complex structureforget holomorphiccharts to smoothchartsexterior-calculusformulationexterior derivativecomplexfield-strength two-formoutputs the Hodge starmetric inputorientation inputgeometric left-handsidegeodesic worldlines+ closed fundamentalformmetric dual in sourcedMaxwell equationimpose compatibilityrequire smoothoperationsimpose compatibilityimpose compatibilityimpose compatibilityretain closednondegenerate 2-formautoparallel curvesconnection curvaturecompactnessgauge symmetry groupdifferentiate at theidentityLorentz isometriescontinuous symmetrygroupsdynamical LorentziangeometryLorentzian geometryLorentzian metricPoisson-bracketgeometryglobal gauge geometryprincipal connectionspin liftconnection curvatureconnection one-formmetric-compatibletorsion-free connectionfix Lorentziansignature+ positive definitenessdivergence-freecurvature combinationmetric tracespacetime curvaturetensor contractionpositive metric+ contact distributionsmooth alternatingcovariant tensor field+ integrabledistributionsupply smoothmanifoldsmooth object/arrowspacessmooth baseadd affine connection+ orientationadd Poisson bracketadd nondegeneratemetric tensor+ compatible analyticatlassmooth event manifoldadd closednondegenerate 2-formtangent bundlecovariant derivativeglobal spinor geometryphase-space geometrysymplectic phasespaceinvert the symplecticformdual bundletensor bundlessmooth sectionmetric and curvaturetensorsrank-two tensor fieldlinear bundlesmooth parameterizedmapsmooth spacetimecurvecurve velocitytimelike tangent vectorconnection derivativecurvature two-formsupplies the spacetimemetric structuresupplies the spacetimemetric structurechoose a Hamiltonianfunctionadjoin the shiftedsourceyields the cone longexact sequenceadd horizontal andvertical differentials+ graded associativemultiplicationretain canonicaltriangulation+ differential 𝑑 ofdegree -1+ differential 𝑑 ofdegree +1has singular chains asa specializationhas singular cochainsas a specializationspecializes to an exactsequence acrossdegreeshas distinguishedexact sequencessource and targetcomplexescommute withdifferentials+ homologyisomorphismsformally invertquasi-isomorphismsshifted derivedmorphismshomology of thederived tensor productnormed domain andcodomainimpose Fréchetdifferentiabilityself-adjointnessantisymmetricmany-particle spacecomplete normedalgebracomplete normweak-derivative normidempotencesummable singularvaluesunitarityobservable algebrafirst variationvariational stationarityoperator adjointsecond-order Laplaciandistributional fieldsantisymmetric sectorsoccupation basisFock representationsymmetric sectorsposition–momentumrepresentationsrapid decayFourier automorphismpartial-derivativeequationfunctional stationarityequationGreen-kernelformulationretain the inducedcomplete normmany-body completionray spacestate-space formalismstate spacetest-space embeddingeigenfunctions on 𝑆²completed tensorproductrequire completenessinduce 𝑙𝑉𝑒𝑟𝑡𝑥𝑟𝑉𝑒𝑟𝑡=√(𝑙𝑎𝑛𝑔𝑙𝑒𝑥,𝑥𝑟𝑎𝑛𝑔𝑙𝑒)+ submultiplicativityimpose compatibility+ continuitykinetic operatorboundednessdense domainGreen kernel when itexistsspectrum+ metrizable, complete+ completenessinduce norm topologyfield equationsincludes quantumevolution equationconstructs a reducedstatespecializes to anormalized stateoperatorstate raysgeneralizedeigenstatescontinuous dualtest functionsnonnegative quadraticformself-adjoint observablespectral resolutionspectral resolution+ definitenessweak-solution spacesprojectivemeasurementspectral measure ofobservableangular orbital basischaracterizescontinuous unitaryevolutionsymmetricmany-particle spacecomposite-systemstate spacetrace one subsystem+ local convexityspecializes to apositive unit-traceoperatorunitary dynamicsequation in oneindependent variabletrajectory equationsreduced densityoperatornonseparabletensor-product statesHamiltonian spectralvaluesnoncommutativeproduct differencesymmetrized productpure-state quadraticformspectrum of aself-adjoint operatoridentify nulldifferencesDedekind realizationforget completenessforget completenessand topologyforget ordercompletenessform ℝ² with complexmultiplicationadjoin a root of 𝑥²+1ordered-pairrealizationpolynomial-quotientrealization𝑎↦ 𝑎+0𝑖forget topology anddistinguished realsubfieldforget algebraicclosurecardinality 𝔠suppliesparticle-number statespace in free orasymptotic regimestake the first-orderlinearizationdifferentiability impliescontinuityautonomous completeevolution generates aflowFourier labels oflattice-periodicfunctionsbosonicoccupation-numberstate spaceformulatesdeterministicconcentrationevolutionreduce a flow toreturns on a sectionreturn-map subclassiteration as discreteevolutioninteger-indexedevolutionreal-parameterevolutionsmooth invertibleevolutiontrajectory from aninitial statedynamically preservedsubsetstationary orbitexactly recurring orbitparameter-dependentfamilyresponse toperturbationsremain-close criterionequilibrium stabilityorbital stabilityattracting invariant setqualitativeparameter-inducedchangeinvariant measuretrivial invariantmeasurable setstangent-growth ratesdeterministic complexdynamicssymplectic Hamiltonianflowsymplectic evolutionformalismspecializes to unitaryquantum evolutionflow on theory orcoupling spacemeasure-theoreticergodicitymicroscopicphase-space dynamicstime-dependent stateevolutionconditions on availableinformationaverages relative toinformationinformation filtrationimpose compatibilityrequire nestedsub-𝜎-algebrasidentify the domainimpose compatibilityfamily members+ Markov propertypush forward theprobability measureintegrate whenintegrable+ mutualindependencetake the first momentGaussian lawsample-averageconvergence understated hypothesesGaussian limit underiid finite-variancehypothesesweak-law convergencestandard-normallimiting lawclassical ensemblemeasurerandom time-evolutionmodelrepresents quantifiedmeasurementuncertaintycomplete Borel volumechoose standardEuclidean volumesupplies an integrationmeasuresupplies the integrandforget the topologygroup integrationimpose measurability+ Borel regularitymeasurable value mapambient 𝜎-algebradomain and codomain𝜎-algebras+ measure 𝜇measurerequire total mass one+ 𝜎-finitenesspositive-operator-valuedmeasuregeneralizedmeasurementoutcomesprobability measureprobability domain+ standard Borel formoutputs Haar measurenormalize on apositive-probabilityeventclassified bydimensionssupplies dimensionexponentsreported by ameasurement resultsingle bound electronvariational equation ofmotionelectromagneticinteractiongravitationalinteractionstrong interactionweak interactionquantum observabledynamical lawretained variablesobservable quantitycutoff and powercountingobservable statisticssymmetry-associatedconservationmatrix-elementconstraintphysical quantitiestheory-relative statequantum systemclassical fieldframeworkclassical dynamicalframeworkeffective descriptionsclassical gravitationaltheorylaw within theorymodel realizationdomain of scalesquantum frameworkrelativistic spacetimeframeworkinteraction coefficientsrenormalized scaledependencetime componentenergy quantitylinear momentumlocal conservation formapproximate internalsymmetrynuclear separationenergyelectron separationenergyimpose rigidityconstraintsstationary-action rulecanonical fieldquantizationelectromagnetic fieldtheoryfunctional-integralquantizationfield quantizationpoint-particledynamicsphase-spaceformulationaction formulationNewtonian formulationform the cotangentphase spaceHamiltonian generatorgenerator of timetranslationtime integralLegendre momentumLagrangian formulationspacetime integralsupplies a local actiondensityPoisson algebra ofobservablesHamiltonian evolutionbracketEuler–LagrangeequationsEuler–Lagrangeequationnet forcemomentum-changeratespatial componentsmomentum dynamicsNewtonian equationsof motionquantitativeaccelerated motionweight histories by theactionpromote canonicalvariables to operatorsmicroscopicHamiltonian evolutionclassical microstatespacepredicts curved lightpathssupplies null-raypropagationlow-momentumexpansionequivalence principlefour-momentumfield equationtest-body free fallgeometric gravityradiative spacetimesolutionsweak-field slow-motionlimitsmall metricperturbationspacetime translationsinertial coordinatesgravitational force lawmass Casimirdynamical spacetimegeometryflat spacetimecurvature dynamicsdynamical LorentzianmetricsuppliesLorentz-covariantkinematicsLorentz invarianceflat relativisticspacetime𝑐→∞ / low-velocity limitrelativistic causal andsymmetry structurerelativistic particledynamicsmatter sourcespacetime eventordered event historylocal causal conesnull coneMinkowski causalstructuretangent four-velocityelapsed proper timerest-frame energy andinvariant massbinding changescomposite massmoving-medium lightspeedunexplained perihelionadvanceether-drift null resultlaboratory gravitationcomposition-independentfree fallsolar light deflectionboost invariance withunequal pathsrelativistic timedilationgravitational frequencyshiftlocal gravitationalredshiftgravitational signaldelayradiative orbital decaystrong-fieldbinary-mergerwaveformindirect evidence fromorbital decayfirst direct detectionsolve in sphericalvacuum symmetrysolve in stationaryrotating vacuumhas a static unchargedidealizationhas a rotatinguncharged idealizationgovernsself-gravitatingcollapsecan form a black holebounded by a causalhorizonform a bound pairobserved throughmerger wavescosmologicalspacetime ansatzhas a global causalboundarysupplies cosmologicalenergy density andpressurespecializes to theconcordancecosmological modelclassical black-holebackgroundderive semiclassicalemissionsets the expansion andthermal historyis realized byhomogeneous andisotropic spacetimemodelsreduces Einstein’sequationevolve the scale factorwavelength stretchingby expansionlocal linear expansionratelow-redshift distancerelationextrapolate to a hotdense pastpredicts relic radiationextends with an earlieraccelerated phasecold gravitating mattercomponentmodeled by 𝛬is constrained by CMBanisotropiessupplies thebackground geometryhas local energy fluxyields local energybalancesupplies ionizingphotonsquantizes orbitalmotiondynamical fieldstationary-sourceregimeparticle force lawfield equationspotentialrepresentationinstantaneous Coulombtermselectron repulsion termattractiveelectron–nucleus termpairwise Coulombtermsexternal electricperturbationelectromagnetic sourcecurrentobserver-relativeelectric fieldobserver-relativemagnetic fieldfield strength 𝐹=𝑑𝐴point-charge lawelectromagneticcouplingexternal magneticperturbationMaxwell dynamicscharge conservationwave solutionspropagating fieldconfigurationclassical radiation fieldoptical interferenceelectric current affectsmagnetismfield lines andinductioninduction lawgenerated anddetectedelectromagnetic wavesradio-wave realizationgauge-invariant loopphaseprecision couplingdeterminationdrives and probesmolecular transitionspredicts barriertransmissiondetermines barrieramplitudesorbital contributionintrinsic contributionoutcome probabilitiesnoncommuting-observableboundFoldy–Wouthuysentermone-electron Diractermsnonrelativistic spinorlimitFoldy–Wouthuysenspin–orbit termexclusionsymmetric exchangesectorantisymmetricexchange sectoroccupation-numberformalismdensity-operatorrepresentationnonrelativistic chargedparticlesneglect spin couplingfermionic occupationconstraintsexchange energy andstructuresemiclassicalcorrespondence modelbound spectrumsemiclassical anddecohered regimesmany-body systemsmolecular quantumstateselectronic and nuclearbinding statesnonrelativistic regimequantum principlesquadratic modeloperator observablesmall perturbationexpansionquantum statequantum dynamics andpredictionscontinuum statetrial-state restrictionprojection quantumnumberorbitalangular-momentumnumberprincipal quantumnumberspin projectiontotal angularmomentumasymptotic scatteringstatesmixed statepure statecoordinaterepresentationspin-1/2 wave equationspin-zero waveequationdifferential evolutionequationmode-loweringoperatormode-raising operatorspin projection onmomentumspin-1/2environment-inducedreduced-statedecoherencenonseparablemany-body statesbaryon quantumnumberflavor labellepton quantumnumbersupports coherentsuperpositionminimum-energy stateabove-ground stateradiative de-excitationdiscrete symmetrylabelparity selection rulestate functionalobservable argumentgives expectationvaluesfailure of classicalequipartitionfrequency-dependentphotoemissionlight quantatwo-valued beamsplittingunexplained magneticmultipletsnonclassical separatedcorrelationsexperimentaldiscrimination of localhidden-variable modelsdiscreteangular-momentumoutcomesquantizedradiation–matterscatteringelectron diffractionmatter-wave amplitudepath-amplitudeinterferenceprobabilistic detectiondistributioninterference ofquantum amplitudesBell-inequality-violatingcorrelationsnonclassicalcorrelation predictionsflux-dependentquantum phasemeasuredcoherence-loss ratetwo-boson bunchingindistinguishabilityinterferenceinterference ofcomposite moleculesenvironment-dependentvisibilitypositive-energyantiparticle realizationformalize localhidden-variableconstraintsis tested throughBell-inequalityexperimentspredicts correlationsincompatible with localhidden-variableboundsSchrödinger-pictureevolution lawquantum states,observables, anddynamicsmixed-state ensemblerepresentationbosonic occupationstatisticsfermionic occupationstatisticsinteractingmany-degree-of-freedomdynamicsquantizednormal-mode algebraperiodic single-particleeigenproblemspecialize quantumtheory to chemicalsystemshasconstraint-dependentthermal responsemacroscopic conditionequilibrium-statesubclasscoordinates by statevariablesequilibriummacroscopic lawstransitive thermalequilibriumenergy balanceentropy and processdirectionthermal state variableentropy state functionfixed-temperaturepotentialclassical phase-spacestatisticsquantum-statestatisticsmicroscopicalternativesprobabilistic statisticalstatecoarse macroscopicstatesquotient by chosenmacroscopicobservablesfixed-energy ensemblefixed-temperatureensembleenergy-and-particleexchange ensemblecanonical stateweightscanonical normalizer𝐹=-𝑘_(𝑚𝑎𝑡ℎ𝑟𝑚 𝐵)𝑇𝑙𝑛 𝑍entropy of ensembleweightslogarithmic state countequilibriummacroscopic entropymacrostate multiplicitylimitcoarse-grainedequilibrium descriptionnondegeneratesemiclassical regimeinfinite-systemasymptotic regimetime-averagejustificationtime-dependent anddriven regimesnear-equilibrium linearresponsesharp equilibriumsingularityphase-distinguishingquantitycontinuous-transitioncritical behaviorshared critical scalingensembles, phases,and fluctuationsmacroscopic materialthermodynamicsadd composition,reaction, and phasevariablesyieldscorrelation-functionidentitiesrelates vertex andpropagatorcanonical constructionparticle–antiparticleconjugationmulti-nucleon EFTleft chiralityright chiralitytwo-point function /Green functionscale-dependenteffective actionmasslesselectromagneticcombinationmassive neutralcombinationneutral gauge-fieldmixingrealizes brokenelectroweak phasemassive chargedcombinationsbroken vacuum phaseintegrate out 𝑊 bosonhypercharge gaugefieldmasslesselectromagnetic gaugebosonelectroweak sectormassive chargedgauge bosonsweak sectorweak-isospin gaugefieldsmassive neutral gaugebosonlow-energy beta-decaydynamicscontact operatorleft-handed chiralfieldslepton matter fieldquark matter fieldright-handed chiralfieldschiral matter kinetictermsbosonic gauge fieldAbelian gauge theoryelectroweak gaugetheorynon-Abelian gaugetheory𝑆𝑈(3) gauge theory𝑈(1) gauge theorynon-Abelian gaugedynamicsBRST structurefunctional determinantcovariant-derivativeinteractionschoose gaugerepresentativespacetime-dependentredundancycontinuous symmetrycurrentgluon quantanon-Abelianself-couplinggluon-field degrees offreedomgluon contributiongluon contributioncolor gauge couplingcolor interactionphysical scalar aftersymmetry breakingnonzero vacuum valueHiggs kinetic andpotential termsphysical scalarexcitationsymmetry-breakingsectorelectroweak orderparameterleft-handed leptoncomponentsleft-handed quarkcomponentsspacelikecommutativitylocal causal structureconfined bound statesspatial integralNoether currentYang–Mills actionfunctional-integralconstructiondiagram expansionperturbativeamplitudesquantizedelectromagneticinteractionphoton quantumphoton gauge fieldcouplingvacuumelectromagnetic modesultraviolet runninglow-energy pionexpansionnonperturbativeconfined phasedressed-quark hadronmodelgluon fieldsgluon fieldgauge self-interactioncolored-to-hadronicconversionregulatednonperturbativeformulationstrongly coupledregimelow-energynucleon/pion degreesof freedomquark fieldsquark matter fieldsquark–gluon couplingcolor-singlet residualinteractionstrong sectorcolor interactionbound-statelow-energyHamiltonianbound-stateperturbativecorrectionsone-transverse-photoncorrectionclassical coherent-fieldlimitstatic nonrelativisticone-photon sectorno-pair relativisticbound-stateHamiltonianquantumelectromagnetismcharged lepton fieldlow-velocitycharged-particle EFTphoton fieldelectromagnetic-currentvertexphoton gauge fieldgauge connection fieldscalar quantum fieldmatter fieldscalar fieldspinor fieldvector fieldinterpolatedone-particle staterigorous distributionalinterpretationconjugate particlesectorscorrelation functionsscale-organized QFTquadratic theorygauge-invariant QFTinteracting theorymultiparticle sectorslow-energyfixed-particle sectorone-particle sectorcoupling / loopexpansionlocal field operatorregulated expressionsasymptotic scatteringoperatorvacuum selectionvacuum statequark-field degrees offreedomquark quantaremove regulatordependencescale dependencebeta-function flowright-handedcharged-leptoncomponentsright-handeddown-type componentsright-handed up-typecomponentsmatrix elementsbosonic scalar fieldHiggs potentialfermionic spinor fieldleft lepton doubletleft quark doubletright charged-leptonsingletright down-type singletright up-type singletchiral fermion kineticand gauge termsgauge symmetrygauge invarianceencodes the localdynamics𝑊^(±) interaction field𝑊^(±) quantumcharged-current weakinteractionYukawa matrices𝑍 interaction fieldneutral-current weakinteraction𝑍 quantumquantum consistencyconditionelectroweak gaugeverticesgauge kineticinteraction termscolor gauge kinetictermscovariant-derivativecouplinggauge-boson masstermsHiggscovariant-derivativeterms𝑊 mass generation𝑍 mass generationhypercharge gaugekinetic termleptonic particle statesquantum symmetryobstructionCPT invariance understandard assumptionsrelativisticspin–statisticsconnectioninteger-spin bosonicstatisticshalf-integer-spinfermionic statisticsnon-Abelian gaugeself-couplingweak gauge kinetictermscharged-fermion massparameterssymmetry-breakingscalar multipletelectromagneticlow-energy sectormatch belowelectroweak scaleQED gauge sectorQCD gauge sectorcharged-currentoperator sectorvanishing divergenceconnection ingredientconnection curvatureminimal gaugecouplingcovariant kinetic termsYang–Mills kinetic termgauge kinetic termscontinuous globalsymmetry theoremgapless modewould-be Goldstonedegreesreorganizedpolarization degreelight-quark chiralsymmetryspontaneously brokenvacuumvacuum orderparameterlight pseudo-Goldstonemodespion multipletpion low-energydegreesymmetry and powercountingquantized radiationfieldexpectednonperturbative gapup/down quark-fielddegrees of freedomup/down quark-fielddegrees of freedomradiative bound-statecorrectionelectron magneticanomalyboundary-dependentelectromagnetic forcenegative neutrinohelicitypredicted neutral weakcurrentpartonic scaling andlater scaling violationsQCD jet topologypredicted weak gaugebosons𝑍-pole andelectroweakobservablesHiggs-field excitationquantum fields on thatbackgroundimposes canonicaloperator bracketsfield and operatormethods for collectivematterlow-energy theoryabout a Fermi surfacescale flow nearcriticalitycommon infraredfixed-point behaviorequilibriumfluctuations determinelinear responsesupplies a physicalquark-sector phaseneutral-kaon decayasymmetryneutron baryonnucleon baryonsproton baryonspin-one gauge bosonscalar bosonelectric chargeelectronmuontau leptonelectric chargecharged-current mixingamplitudescolor couplingobservable asymptoticstatescolor-neutral QCD stateQCD compositeelectric chargeelectromagneticcouplingelectron–nucleusbindingproton Coulombrepulsionatomicelectromagneticregimemolecular electronicbindinginteratomicelectromagneticbindingproton Coulombinteractionelectronic constituentselectric chargecaptured boundelectronpolarization statesthree fermiongenerationscolor-neutral fermioncolor-charged fermionfirst fermiongenerationsecond fermiongenerationthird fermiongenerationdown quarkelectronelectron neutrinoup quarkcolor gauge bosonelectromagnetic gaugebosoncharged weak gaugebosonneutral weak gaugebosoncolor quantum numberbaryonmesonnucleon hadroncharged leptonscharged leptonneutral leptonpionelectric chargeelectron neutrinomuon neutrinomass propertytau neutrinocoherent flavoroscillationnonzero mass-squareddifferencesflavor–mass mixingbottom quarkcharm quarkcolor quantum numberdown quarksea-quark contentstrange quarktop quarkup quarknet valence contentsea-quark contributionsea-quark contributioncharm quarkmuonmuon neutrinostrange quarkparticle contenthigher-dimensionoperator extensionelectric chargeelectric chargebottom quarktau leptontau neutrinotop quarkelectric chargeelectric charge𝑢𝑑𝑑 net valencecontent𝑢𝑢𝑑 net valencecontentelectric chargehypercharge couplingflavor-changing weakprocesscharged-currentchannelneutral-currentchannelflavor-changingcharged currentweak-isospin couplingmixing parameterbaryon number onecomplete chiralcontent cancelsanomalieslepton flavorleptonic quantumnumberquark baryon numberquark flavorintegrate outelectroweak-scalefieldsmassive-vectorpolarizationmassive-vectorpolarizationapproximate chargeindependencephoton excitationcontentabsorbed radiationquantumweak-interaction flavorbasispropagation massbasiselectron flavormuon flavortau flavorcharge-conjugateweak-interactionchannelelectron antineutrinoflavormuon antineutrinoflavortau antineutrino flavorweak-interaction basispropagation basisrelative propagationphaseselementary quarkspecieselementary leptonspecieselementary gaugebosonselementary Higgsbosonelectron antiparticleproton antiparticleneutron antiparticlequark antiparticle classCP violation in weakdecaysflavor-changing weakphasesmissingelectron-neutrino fluxpointlike nucleonconstituentsuniversal corpusclewith fixedcharge-to-mass ratiocharge quantizationand elementary chargeelectron chargemagnitudephoton momentumtransferpositive electron trackfirst identifiedantiparticlenew penetratingcharged particleinverse-beta detectionreactor antineutrinodetectionparity violation in betadecayneutrino helicity signdistinct neutrino flavorneutrinoneutral-current eventscharmonium resonancethird charged leptonthird lepton familymemberbottomoniumresonancehard gluon radiationcharged weak bosondiscoveryneutral weak bosondiscoveryprecisionradiative-consistencyteststhird-generationup-type quarkpredictedthird-generationpartneratmospheric flavordisappearancelepton mixingparameterssolar flavor conversionsolar mixingnew spin-zero bosonnear 125 GeVcompletion ofpredicted elementaryfield contentmobile and boundelectronic constituentpaired electronicquasiparticlesdominant microscopiccouplingcan be absorbed by anucleuscan form a captureproductproducesanalyte-dependentactivitycontributeslight-nucleus reactionssplits into lighternucleitwo nuclear reactantsselect a permittedfusion channelemitted alpha particlenuclear constituentextended chargedistributionmass andcharge-radiusdependenceneutron countseparation energytotalnuclear quantumstatesproton countunstable nucleartransitionbeta-minus channelbeta-plus channelelectron-capturechannelelectron productelectron-antineutrinoproductproton productelectron-neutrinoproductpositron productelectron-neutrinoproductgamma photontwo neutronconstituentsneutron constituentfree-neutron betadecayneutron constituent𝐴=𝑍+𝑁 contribution𝐸=𝛥 𝑚𝑐²Coulomb contributionto nuclear structuresystematic nuclearinteraction expansionthree-nucleonoperatorsnuclear bindingtwo-nucleon bindingtwo-nucleon sectoratomic nucleusbulk collectivedescriptionself-consistentone-body fieldvalence-space effectiveHamiltoniannuclear multipolecouplingenergy eigenvaluemetastable statetotal angularmomentumneutronnucleon constituentsprotonpotentialrepresentationsame 𝐴 familysame 𝑁 familysame-𝑍 nuclide familylong-range componentexchanged pion fieldtwo protonconstituentsproton constituentproton constituentelement identity𝐴=𝑍+𝑁 contributionalpha decay channelbeta decay channelgamma transitionchannelnucleon interactionmany-nucleon bindingcontributionisospin doubletisospin tripletnuclear-state paritylarge-angle alphascatteringnuclear atom modelmissing energy andmomentumquantitativebeta-decay dynamicsrecurring enhancedstabilityX-ray frequency tracksnuclear chargesame element, distinctmassesmass-resolved nuclearspeciesnoninteger masses andpacking fractionneutral nucleonpion track and decaychainhydrogen nucleusemitted from nitrogenionic-core or nuclearconstituentassigned as adistinguishableatom-flow labelrealized as a calibratednuclear clocksupplies eachsequential nucleartransformationabundance differencesresolved by calibratedion massessupplies fissileconsumption andproduct inventoriesincludes radioactiveisotopic membersphoton-inducedionization𝑗𝑗 coupling regimeLS coupling regimestationary energystatesatomic quantum statesionization or electronattachmentelectron removalmany-electron atomatomic nuclei andelectrons reorganizedin molecular statespecified nuclearcompositionhistorical nuclearmodeltransition frequenciesatomic bound-statedynamicsneglect nuclear recoilleading nonrelativisticCoulomb modelfinite-mass correctionrelativistic atomicdescriptionoccupation basisgrouped by principalshellself-energy correctionradiative level splittingvacuum-polarizationcorrectionenergy levelangular-momentumlabelstate changeupward radiativetransitionelectric-dipole channelvacuum-inducedemissionfield-stimulatedemissiontwo-body reducedmassmany-electron basisexpansionelectron–nucleusbound systemconfiguration basiscomponentsmany-electronrepulsionprincipal atomicbinding interactionangular-momentumsubshellantisymmetric meanfieldgross hydrogenspectrumcharged residue𝑗𝑗-coupled labels^(2𝑆+1)𝐿_(𝐽) labelsone-electron basis /mean-field orbitalspherical effectivepotentialground-state densityformulationsingle-determinantmean fieldproduct-state meanfieldeffective one-electronstatesseparate translationalmotionbound-state radiativeexpansionexact one-electronwavefunctionneutral hydrogenone-electron ionsubshell labelprincipal shell labelfinite-mass Rydbergcorrectionrelativistic splittingquantized-orbitsupplementscreened effectivepotential𝐸1 selection rulesemitted photonadditional photon indriven modeatomic breakupthresholdfirst ionizationthresholdatomic ground stateatomic excited statesatomic-state parityelectron repulsion termelectron–nucleusattraction termregular hydrogen lineseriesdiscrete hydrogenspectrumprecision bound-statediscrepancyproton charge-radiussensitivitydiscrete excitationthresholdsquantized atomicexcitations2𝑆_(1/2)–2𝑃_(1/2)splittingprecision hydrogenradiative shiftquantitative atomictheoryrepeating atomic orionic constituentsspin-dependentordering contributionconfine motion to twodimensionsyields quantizedtransport in amagnetic fieldinteracting many-bodymatterelectronic materialsinteractingelectron–ion systemtranslationally orderedsolidcoherent many-bodymodelong-lived effectiveexcitationlattice-vibrationquasiparticlecollective lattice modeideal periodicgeometrydual translation latticecollective ionicdisplacementquantized normalmodeperiodic one-electronHamiltonianperiodic translationsymmetry impliesBloch formBloch-form eigenbasisenergy bands overcrystal momentumlocalized-orbitaltruncationweak-periodic-potentialapproximationhopping-model bandsweak-potential bandsmetallic band fillingfilled-band insulatorcontrollable gappedconductorband crossing atchemical potentiallow-energy occupationboundaryfilled bands separatedby a gapthermally andchemically accessiblegapcollective momentorderingspontaneous netmagnetizationtwo-state lattice-spinmodelcoherent pairedquantum phaselattice-mediatedpairing regimecoherent condensateof pairslattice-mediatedeffective attractionweak-coupling pairedmean-field theorylocal-interaction latticemodellow-energyquasiparticles near aFermi surfacelong-lived fermionicquasiparticlescollective materialphase changeground-state densityformulationstructure tested bydiffraction intensitiesqualified by dispersionspecialize to chemicalmeasurandsquantitativeelectrostatic-forcecomparisoncompares reactantamounts to coefficientssupplies the balancedreaction relationincludes identifiedsubstancesincludes mixturessampled as onesubstanceincludes compoundsincludes elementalsubstancesincludes atomicspeciesincludes ionic speciesincludes molecularspeciessuppliesentity-countingquantitysupplies SI amountunitconverts mass andamounthas simplest-ratio formhas molecular-countformsupplies formula ratioshas compositionrepresentationrequires balancedmass accountingconstrains fixedcompositionsupports integralcomposition ratiossets reactioncoefficientsquantitativeclosed-systemaccountingreproducible fixedcompositionincludes homogeneousmixturesincludes conventionallyorganic substancesincludes conventionallyinorganic substancessupplies amount-basedcompositionsupports amount-ratiocalibrationconverts measuredsignals into chemicalamountsnegative ionpositive ionmolecular ionization orelectron attachmentdescribed byconnectivity andgeometryhas quantizedrotational degrees offreedompartitions elements byblockidentifies the fillingblockrealized as elementtableforms vertical familiesforms shell-filling rowsorders elements byproton numberrecurrence fromelectronic structuresupports bondingcapacityexplains screenedattractionpredictive gapsstrengthenedperiodicityeka-aluminiumprediction testedordering by atomicnumbersupplies sharedelectron densityparticipates in electronbookkeepingcontributes toelectron-removalenergytracks formal electrontransferorganizes d-blocktrends and familiesmaps comparativeelectron attractionmaps electron-additionenergeticsmapsmodel-dependentatomic sizemaps recurring formalvalence stateshelps estimate ioniccharactercontributesbond-polarityestimatescontributeselectron-additionenergeticsconstrains recurringconnectivity patternsneutral atomicrepresentativethreshold energyelement identity byatomic numberincludes axial-overlapbondingincludes side-onbondingclassifies orbitalsymmetryclassifies side-onorbital symmetrycontributes axial C–Obondingcontributes C–O pibondingtwo-dimensionalvalence modelconnectivity graphnuclear arrangementaccessible conformerslocalized bondingdescriptiondelocalized orbitaldescriptionlocalized orbital basisassigns formal chargesrequires multiplecontributorsqualitative shapepredictionstabilizes molecularconnectivitystabilizes ionic latticesincludes hydrogenbondingbiases conformationalpopulationscontributeselectrostatic couplingspecialized to spatialidentitysupplies delocalizedorbital frameworkcontrols mixingnonidealitysets spectroscopicselection patternsenables dipole-activevibrationsconstrained bymolecular spectrarepresented bydirectional hybridorbitalsrepresented bylocalized electronpairingclassified by invariantsymmetry operationsstabilizes molecularstructurestabilizes orderedmaterial structureincludes covalentbonding descriptionsincludes ionic bondingdescriptionsincludes directionalhydrogen bondingassigned amodel-dependent bondmultiplicitysupplies a finiterepresentationexpands orbitalsnumericallyseparates electronicand nuclear motiondefines fixed-nucleielectronic problemincludes first-principlesmethod familysingle-determinantmean fielddensity-basedformulationdeterminant expansionexponential correlatedansatzadiabatic energylandscaperestoring-forcelandscapeincludes rotationaltransitionsincludes vibrationaltransitionsincludes dipole-activeabsorptionincludes polarizabilityscatteringincludes electronicabsorptionincludes nuclear-spinresonancerelates absorbance andconcentrationfrequency-shiftedscattered lightnuclear resonance incondensed mattercalculates electronicand nuclear energeticssupports nuclearmotion on anelectronic surfaceexplains trendsthrough electronicstatesincludes mean-fieldstarting pointincludes determinantexpansionincludes exponentialwavefunction methodincludes density-basedmethodsdefines energetic pathcoordinatescontainsdividing-region saddleconstrains moments ofinertiarealized by opticalabsorbancemeasurementproducesfrequency-shiftedscattered photonssupplies forces fornuclear motionspecializes electronicstructure tocoordinated metalcentersrotational-statestructure tested byresolved spectramulti-configurationextensionexponential correlatedextensioncorrelation beyondmean fieldspecifiesstandard-statereaction changerelates 𝛥ₘ𝑎𝑡ℎ𝑟𝑚𝑟𝐺^(𝑐)𝑖𝑟𝑐 to 𝐾supplies apressure-adapted statefunctionsuppliescomponent-wisethermodynamic drivingforcessupplies the fixed-𝑇,𝑝potentialsets referencechemical potentialreaction-statedifferencemakes thermochemicalsums pathindependentactivity condition forequilibriumhas activity-ratioconstantminimum underconstraintsqualitativeperturbation responseconstrains coexistencedimensionsquantitativereversible-reactionpatternspath-independent heatsumsdefines dimensionlessreferencethermodynamicreparameterizationsets phase coexistenceis thermal chemicalmeasurementgovernselementary-stepconcentrationdependencespecializes to protontransferspecializes to phasedissolutiondeterminesspontaneous responsedirectionmeasured throughcalibrated heatexchangehas charge-weightedcompositioncontrols a leadingnonideality variableideal mixing referenceideal vapor-pressurerelationinfinite-dilutionrelationhasparticle-count-dependentshiftsopposed by pressuredifferenceincludes ionic solutionsforms solvated mobileionsquantified byhydrogen-ion activitysets saturationconditionsets hydrogen-ionactivityforms donor–acceptoradductshas ideal single-siteformprovides active-siteenvironmentdominates dispersedparticlesself-assembles aboveassociation rangeincludes associationcolloidstested throughsaturating monolayeruptakedilution-dependentionic conductiondilute ideal relationforms thermodynamicreaction quotientsets concentrationdependenceforms ionic conductionpathchargedelectrode–electrolyteinterfaceprovidesstationary-phaseretentionpopulates reactivesurface sitesdescribesproton-transferionizationtested across aneutralization curvedescribes compositionand reaction at phaseboundariesdescribes conjugateproton-transferequilibriagoverns finitebuffering responseassigned a statedcomposition scaleassignedthermodynamiceffective compositionparameterized by anonideality coefficientassigned a conditionaldissociation constantpermitscontext-dependentdonor and acceptorrolesassigned reversibleinterfacial free energyper arearepresented by uptakeat fixed temperatureadsorbs and changesinterfacial free energyforms the designatedmedium componentforms a dissolvedcomponentsupplies a kinetic statevariableidentifiescondition-dependentrate controlconstrains theobserved rate formdescribes reactionratessupplies a normalizedprogress variablerepresented by aregime-specific ratelawforms mechanism stepimplies kinetic formsets apparent slopeeliminates short-livedintermediatesgas-collision ratemodelstatisticalbarrier-crossing rateincludes same-phasecyclesincludes interfacialcyclesdescribeslight-initiated reactionpathwaysactivated temperaturedependencetime-resolved transientconfigurationsresolvedbond-rearrangementdynamicsforms syntheticoperationsincludesoxidation–reductiondistinguishessubstitution pathwaysdistinguisheselimination pathwaysresolves bond-additionstepsdefines barriercontributiondescribeselectronically excitedmolecular statessummarized by a netchemical equationrepresented by analternative catalyticcycleassociated with alower accessiblebarrier pathwayspecializes inorganicchemistry to biologicalsettingsincludes ionic solidsincludes coordinationentitiescoordinates centralatomdistinguishescoordination spherehas coordination countstabilizes coordinationentityelectrostatic d-levelsplittingextended by covalentorbital mixingincludestransition-metalcomplexesoverlaps metal–carboncompoundsundergoes ligandexchangesupplies entering andleaving groupsisomer counts and iontestsrealizes extended ionicinteractionacts as electron-pairdonorclassified bypoint-group symmetryforms metal-basedimaging and therapyagentspredicts d-leveltransitionsforms molecularcatalyst intermediatesforms bond-activationsteporganizes metal-ionorbital occupationsidentified throughselective chemicalevidenceapproximated byelectron-domainrepulsionassigned a formalmetal oxidation staterepresented bysymmetry-adaptedorbital mixingproduces ahigher-coordinateformal oxidationproductsupplies selectivecomplex formationsupplies bond-formingcatalyst turnoverincludes hydrocarbonsincludes the𝑚𝑎𝑡ℎ𝑟𝑚𝐶=𝑂 motifis the definingstructural motifincludescarbonyl-containingcompoundsincludes heterocycliccompoundsincludes compoundsdistinguished byconnectivityincludes chiralstructuregives mirror-relatedpairforms bond atelectrophilic centeraccepts electrondensityappears in stepwisepathwaysappears in stepwisepathwaysplanned by backwardtransformslaboratory access to abiological productcrystal handednesslinked to opticalrotationmirror-relatedmolecular dissymmetrydiffers by labeledconnectivityexcludes impropersymmetry operationsseparated in a chiralenvironmentacts as electron-pairdonoracts as electron-pairacceptorconnects elementarystepsplans backward fromtargetssupplies bond-formingadditionssuppliesunsaturation-formingstepssupplies concertedbond reorganizationstested by NMRobservablesrepresented bydelocalized resonancecontributorsforms a recurringreactive substructureassigned aromatic ornonaromatic characterassignment tested byvibrational bandsassignment tested bymagnetic-resonancecontextrepresented by cyclicdelocalized orbitalssuppliesgroup-replacementtransformationsincludes identificationincludes amountestimationsupplies calibratedobservationscontrolsrepresentativenessprovides characterizedreferenceincludes separativeanalysisincludesphase-distributionmethodsgas mobile phaseliquid mobile phaseincludesmass-to-chargeanalysisincludes opticalquantitationincludes stoichiometricvolumetryincludes diffractionstructure analysisincludesmatrix-matchedcalibrationmodels responsewithin the samplematrixspecializes massanalysis to isotoperatiosseparated pigmentbandsdiffraction convertedto structuremass-resolved isotopebeamscreates gas-phase ionsfor analysisincludespotential-sweepelectroanalysismodeled by a validatedresponse relationreports concentrationas a measurandqualified by ameasurement-uncertaintymodelassigned aprocedure-specificdetection capabilitycouples electron andion transfersupplies ionicconductorsupplies electronicinterfacehas standard-statereferenceactivity-dependentequilibrium potentialincludespower-producing cellsincludes electricallydriven cellsrelates charge andtransformed amountcoupled materialoxidationsustained current fromrepeated cellscharge–amountproportionalitylogarithmicconcentrationdependenceforms electron–ionboundarycombined intostored-energy deviceoperated withcontinuing reactantfeedcouples charge withspecific ion uptaketested bypotential-sweptcurrent responsedevelops interfacialcharge organizationassigned a departurefrom equilibriumpotentialsupports interfacialcharge-transfer ratesuses a two-directioncharge-transfer modelrelates current tokinetic potentialdepartureprobed throughscan-rate-dependentcurrentssupplies an interfacialthermodynamiccoordinateassigned a reactionGibbs-energy changesupplies drivenelectrode andelectrolyte interfacesdescribes radioactivenuclides throughchemical identityhas characteristicdecay modesincludesradiation-inducedreactionsincludes activationmeasurementsupplies nuclidic decayclockspecifies parent anddaughter nuclidessuppliesparent–daughter andingrowth relationsincludes carbon-14chronometrycontrols actinidestreamsactivity-guidedchemical fractionationchemically identicalradioactive formsknown-age samplesand modern carbonquantified throughcalibrated isotoperatiossupplies theequilibrated spikesupplies a radioactivesignaling or therapycomponentFinite setCountable setIndexed familyTransitive setWell-foundedrelationOrdinalCardinalEmpty setPower setCantor’stheoremFinite ordinalSuccessorordinalLimit ordinalFirst infiniteordinal 𝜔Finite cardinalInfinite cardinalCountableordinalCountableinfinity ℵ₀OrdinalarithmeticTransfiniterecursionFirst uncountableordinal 𝜔₁SuccessorcardinalLimit cardinalEpsilon-zeroordinal 𝜖₀Aleph hierarchyBeth hierarchyClass of allordinals OrdCardinality ofthe continuum 𝔠ContinuumhypothesisGeneralizedcontinuumhypothesisLarge cardinalStronglyinaccessiblecardinalMeasurablecardinalSupercompactcardinalSetPointed setFunctionZermelo–Fraenkelset theory (ZF)Axiom of choice(AC)Well-orderingtheoremZermelo–Fraenkelset theory withChoice (ZFC)Von Neumannzero 0Von NeumannsuccessorVon Neumannone 1CumulativehierarchyBinary relationEquivalencerelationPreorderPartial order /posetBounded posetDirected setJoin-semilatticeMeet-semilatticeTotal ordergroup +total ordermeet +joinWell-orderDirected-completepartial orderLatticeTotally orderedgroupBounded latticeDistributivelatticegroup +latticeorderlattice +monoid withresidualsPointed CPObounded +distributiveCompletelatticeLattice-orderedgroupResiduatedlatticering +total orderBoundeddistributivelatticeFrame / completeHeyting algebraOrdered ringBooleanalgebraHeytingalgebraCompleteBoolean algebrafield +total orderOrdered fieldMonotone mapGaloisconnectionFirst-ordersignatureFirst-ordertheoryModal Kripkemodelsignature+ carrierFirst-orderstructurePropositionalintuitionisticKripke modeltheory +structuresatisfying itModel of atheoryNormal modalalgebraFormal proofsystemConsistentformal theorySyntacticallycomplete formaltheoryconsistenteffective theory+ arithmeticcodingGödel’s firstincompletenesstheoremconsistenteffective theory+ internalprovabilityGödel’s secondincompletenesstheoremHilbert’sprogramSemanticconsequenceGödelcompletenesstheoremCompactnesstheoremconsistentfirst-ordertheorySatisfactionrelationAlgorithmDecisionproblemTuring machineComputablefunctionComputablyenumerable setUniversal TuringmachineDecidableproblemHaltingproblemUndecidableproblemChurch–TuringthesisGödelnumberingMany-onereductionCategoryCartesiancategoryFinitely completecategoryGroupoidMonoidalcategoryPreadditivecategorySmall categoryThin categoryAdditivecategoryBraided monoidalcategoryCartesian closedcategorycategory +cosimplicialdiagram datacategory +simplicialdiagram dataDaggercategoryobjects +monoidalbasePresheafSiteAbeliancategoryClosed monoidalcategoryCosimplicialobjectEnrichedcategoryfinite limits +exponentialsSimplicialobjectSymmetricmonoidalcategoryElementarytoposCompact closedcategoryGrothendiecktoposFunctorNaturaltransformationAdjunctionCategoricallimitCategoricalcolimitRepresentablepresheafQuiver / directedmultigraphUndirectedmultigraphDirected acyclicgraphHypergraphSimple graphAbstractsimplicial complexBipartite graphForestMatroidPlanar graphTournamentWeightedgraphOrientedmatroidTreeConnectedgraphCompletegraphProper vertexcoloringGraphisomorphismAlgebraicsignatureQuasigroupsignature+ carrieroperationsAlgebra for afinitary signature(𝛺-algebra)LoopRackQuandleCongruencerelationQuotientalgebraMagmaSemigroupMonoidCommutativemonoidGroupAbelian grouptwocompatiblemonoidsSemiringRingCommutativeringDivision ringring action onan abeliangroupModule over aringFieldAffine spaceAlgebraicallyclosed fieldfield action onan abeliangroupPerfect fieldVector spaceComplex vectorspaceDual vectorspaceLie algebraSymplecticvector spaceAlgebra over afieldAssociativealgebraTensor-productvector spaceCoalgebraExterioralgebraUnital associativealgebra*-algebraalgebra +coalgebracompatibilityClifford algebraCommutativeunital algebraover a fieldGrassmannalgebraBialgebraGammamatricesHopf algebraSlaterdeterminantOperatorcommutatorOperatoranticommutatorDirect sum ofvector spacesPolynomial ringField extensionAlgebraic fieldextensionSeparable fieldextensionNormal fieldextensionSplitting fieldFieldautomorphismGaloisextensionGalois groupFixed fieldFundamentaltheorem of GaloistheorySolvable groupsplitting field+ its solvableGalois groupSolvability byradicalsQuadratic formnormal +separable fieldextensionIdealQuotient ringgroup +carrieractionGroup action𝐺-setCircle group𝑈(1)Lorentz groupPoincaré groupSpecial unitarygroupSpin groupgroup +vector spaceactionLie algebra +vector spaceactionLinearrepresentation ofa groupIrreduciblerepresentationRepresentationof a Lie algebraSpinorrepresentationUnitaryrepresentationClebsch–GordancoefficientCharacter of afinite-dimensionalrepresentationPeano systemNaturalnumbers ℕDifference pairs ofnatural numbersIntegers ℤInteger fractionpairsRationalnumbers ℚIntegral domainDedekinddomainGCD domainValuation ringFinite fieldNumber fieldUniquefactorizationdomainValued fieldGlobal fieldPrincipal idealdomainReal closedfieldRing ofintegersCompletevalued fieldDiscretevaluation ringEuclideandomainLocal field𝑝-adic fieldValuationCompletion at avaluationResidue fieldPlace of anumber fieldLocal pointAdele ringEverywherelocally solublevarietyLocal–globalprincipleHasse–MinkowskitheoremVariety violatingthe Hasseprinciplevariety +completion +chosen localsolutionSuccessorstructurePrime idealpresheaf+ siteSheafSheaf of groupsSheaf of ringsRinged spacespace +sheaf ofringsLocal ringLocally ringedspaceNoetherian ringArtinian ringNoetherian+ localregularitySchemeAffine schemeRegular localringAlgebraic spaceComplete localringNoetherianschemeReducedschemeschemeover afieldSeparatedschemeAlgebraicvarietyIntegralschemeRegularschemeScheme over abaseProjectiveschemeLocalization of acommutative ringPrime spectrumSpec(𝑅)Stalk of a sheafSmooth projectivequadricRational pointMorphism ofschemesTopologicalspaceCompact spaceLocally EuclideanspacePseudometricspaceSecond-countablespace𝑇₀ spaceUniform spaceConnectedspaceFirst-countablespaceLocallycompact spaceMetric space𝑇₁ spaceCompletemetric spaceHausdorffspaceLocally connectedspacesemigroup+ topologySeparablemetric spaceTotallydisconnectedspacecompact +Hausdorffcompact+ metricgroup +topologylocalcompactness+ Hausdorffmanifoldcompatibilitymonoid +topologyRegular 𝑇₁spaceTopologicalsemigrouptopologicalspaces +covering mapZero-dimensionalspaceCompactHausdorff spaceCompact metricspaceLocally compactHausdorff spaceNormal 𝑇₁spacePolish spaceTopologicalgroupTopologicalmanifoldTopologicalmonoidtopologicalspaces +locally trivialprojectionTychonoffspaceFiber bundlering +topologyTopological ringLocalefield +topologyTopologicalfieldfunction +domain/codomaintopologiesContinuousmapHomeomorphismQuotient spacetopology +basepointPointedtopological spaceTopological pairPath-connectedspaceCompactlygenerated spaceContractiblespace𝐻-spaceSimply connectedspaceCovering spaceCW complexSimplicial setHomotopyHomotopyequivalenceLoop space 𝛺 𝑋Fundamentalgroup 𝜋₁(𝑋,𝑥₀)Higher homotopygroup 𝜋ₙ(𝑋,𝑥₀)Singular chaincomplexHomologygroupSingular cochaincomplexCohomologygroupCohomologyringHomotopy typegroupoid +smoothstructureSmoothmanifoldbundle +groupactionComplexmanifoldgroup +smoothmanifoldLie groupoidManifold withaffine connectionPoissonmanifoldPseudo-RiemannianmanifoldReal-analyticmanifoldRiemannianmanifoldSmooth manifoldwith boundarySymplecticmanifoldVector bundleCotangentbundleTangent bundlecomplexmanifold +metricContactmanifoldDifferentialformFoliatedmanifoldLie groupLorentzianmanifoldOriented smoothmanifoldPrincipalbundleTensor bundlevector bundleover smoothbaseCompact LiegroupConnection on avector bundlede RhamcomplexHermitianmanifoldPrincipalconnectionSmooth vectorbundleTensor fieldCurvature formKähler manifoldmetric +orientationHodge staroperatorLevi–CivitaconnectionGeodesicRiemanncurvature tensorSpin structureRicci curvaturetensorScalarcurvatureEinstein tensorSmooth curveTangent vectorExteriorderivativeBigraded objectGraded objectChain complexCochaincomplexExact categoryDoublecomplexGrothendieckabelian categoryModel categoryTriangulatedcategoryDerivedcategoryDG-categoryDifferentialgraded algebraExact sequenceLong exactsequencetwo chaincomplexes +degreewisemorphismsChain mapQuasi-isomorphismProjectivemoduleInjectivemoduleExt functorTor functorMapping coneDedekind-cutreal lineCauchy sequencesof rationalsReal numbers ℝOrdered-paircomplex fieldPolynomial-quotientcomplex fieldComplexnumbers ℂlinear +topologicalcompatibilityLinear operatorSeminormedvector spaceTopologicalvector spaceNormed vectorspaceInner-productspaceLocally convexspacePartial differentialequationBounded linearoperatorDifferentialoperatorFréchet spaceBanach spaceCalculus ofvariationsDensely definedoperatorFouriertransformLaplaceoperatorAdjointoperatorcompletenormedalgebraFunctionalderivativeSchwartz spaceBanach algebraBanachalgebra +involutionGreen functionHilbert spaceProjectionoperatorSelf-adjointoperatorSobolev spaceSpace ofdistributionsSphericalharmonicUnitaryoperator𝐶^(*)-algebraOperatorspectrumPositiveoperatorProjectiveHilbert spaceFock spaceRigged HilbertspaceSpectralmeasureTensor-productHilbert spaceTrace-classoperatorBosonic FockspaceFermionic FockspacePartial traceSpectral theoremfor self-adjointoperatorsStone theoremOrdinarydifferentialequationfunction +normeddomain andcodomainDifferentiablefunctionDerivativeLebesgueintegralSelf-mapDynamicalsystemDiscrete-timedynamical systemContinuous-timedynamical systemOrbit /trajectoryInvariant setParameterizeddynamical systemFixed point of adynamical systemPeriodic orbitMeasure-preservingdynamical systemDynamicalstabilityErgodic dynamicalsystemLyapunovstabilityAttractorBifurcationLyapunovexponentChaoticdynamicsHamiltoniandynamical systemSmooth flowPoincaré returnmapordered family+ ambientmeasurablespaceprobabilitydomain +measurablemapFiltrationRandomvariableFilteredprobability spaceprobability+ filtrationStandardprobability spaceprobability +indexedrandomvariablesStochasticprocessMarkov chainProbabilitydistributionExpected valueIndependentrandom variablesConditionalprobabilityNormaldistributionConvergence inprobabilityLaw of largenumbersCentral limittheoremConditionalexpectationMeasurablespaceMeasure spacefunction +measurabledomain/codomainBorel measurablespaceMeasurablefunctionProbabilityspace𝜎-finitemeasure spaceregularmeasure onLCH spaceRadon measurespacetopologicalgroup + localcompactnessHaar measurePositive-operator-valuedmeasureLebesguemeasurePhysicalsystemPhysical theoryPhysical lawPhysicalquantityDegree offreedomObservablePhysical scalePhysical statePhysicalsymmetryFundamentalinteractionPhysical modelConservationlawCouplingconstantEquation ofmotionEffectivedescriptionEnergyContinuityequationBinding energyPhysicaldimensionDimensionalanalysisClassical fieldtheoryActionfunctionalClassicalmechanicsConfigurationspaceHamiltonianLagrangianLagrangiandensityCanonicalmomentumHamiltonianmechanicsLagrangianmechanicsPhase spacePoisson bracketStationary-actionprincipleEuler–LagrangeequationNewtonianmechanicsClassical pointparticleForceLinearmomentumNewton’s lawsof motionGalileo’sinclined-planeexperimentsRigid-bodydynamicsSpacetimeSpecialrelativityGeneralrelativityMinkowskispacetimeEquivalenceprincipleGravitationLorentzsymmetrySpacetimemetricFour-vectorInertial framePoincarésymmetryProper timeStress–energytensorEinstein fieldequationEnergy–momentumfour-vectorGeodesicmotionRelativisticparticlemechanicsWeak-fieldgravityNewtoniangravitationCausalstructureFour-velocityLight conePhysical eventWorldlineMass–energyequivalenceCavendishtorsion-balanceexperimentFizeaumoving-waterexperimentMercuryperihelionanomalyMichelson–MorleyexperimentEötvöstorsion-balanceexperiments1919 eclipselight-deflectionobservationsKennedy–ThorndikeexperimentIves–StilwellexperimentPound–RebkaexperimentShapirotime-delaymeasurementHulse–Taylorbinary-pulsarobservationsGW150914gravitational-wavedetectionBlack holeEvent horizonSchwarzschildspacetimeKerr spacetimeGravitationalcollapseBinary black-holesystemblack-holebackground +quantum fieldsHawkingradiationGravitationalwaveGravitationallensingCosmologicalprincipleFLRWspacetimeFriedmannequationsExpandinguniverseHot Big BangmodelCosmic microwavebackgroundCosmologicalinflationDark matterDark energy𝛬CDMcosmologicalmodelCosmologicalredshiftHubble–LemaîtrelawBig BangnucleosynthesisFine-structureconstantClassicalelectromagnetismElectricfour-currentElectromagneticfieldElectromagneticfour-potentialElectric fieldMagnetic fieldMaxwellequationsElectrostaticsLorentz forcelawCoulomb lawCoulombpotentialElectromagneticwaveElectromagneticradiationYoung’sdouble-slitexperimentØrsted’s compassexperimentFaraday’sinductionexperimentsHertzelectromagnetic-waveexperimentsPoynting vectorQuantummechanicsQuantumsystemQuantum stateMixed quantumstatePure quantumstateDensityoperatorQuantumobservableWavefunctionBorn ruleCanonicalcommutationrelationsQuantummeasurementRelativistic waveequationsUnitary timeevolutionDirac equationKlein–GordonequationQuantum angularmomentumSecond-quantizedformalismSpinUncertaintyprincipleAnnihilationoperatorCreationoperatorIdentical quantumparticlesNonrelativisticquantummechanicsOrbital angularmomentumQuantumnumberSpin one-halfBose–EinsteinstatisticsFermi–DiracstatisticsOccupation-numberstatePauli equationQuantumbound stateQuantumharmonicoscillatorQuantumscattering theoryScatteringstateSchrödingerequationMany-bodyquantummechanicsPauli exclusionprincipleQuantumperturbationtheoryQuantumvariationalmethodQuantumdecoherenceQuantumentanglementQuantumsuperpositionGround stateExcited stateParityQuantumexpectation valueAnomalousZeeman-effectobservationsBlackbodyspectrum andultravioletcatastrophePhotoelectric-effectexperimentsStern–GerlachexperimentComptonscatteringexperimentDavisson–Germerelectron-diffractionexperimentSingle-particledouble-slitexperimentsEinstein–Podolsky–RosenargumentBell-testexperimentsAharonov–BohminterferenceexperimentsCavity-QEDdecoherenceexperimentsHong–Ou–MandelexperimentFullerenematter-waveinterferenceBell theoremQuantumtunnelingThermodynamicsystemThermodynamicstateThermodynamicequilibriumThermodynamicstate variableStatisticalmechanicsTemperatureZeroth law ofthermodynamicsFirst law ofthermodynamicsSecond law ofthermodynamicsClassicalstatisticalmechanicsQuantumstatisticalmechanicsMicrostatespaceStatisticalensembleEquilibriumthermodynamicsMacrostatespaceMicrocanonicalensembleCanonicalensembleGrand-canonicalensembleNonequilibriumstatisticalmechanicsThermodynamicentropyHelmholtz freeenergyBoltzmanndistributionStatisticalpartition functionGibbs entropyBoltzmannentropyThermodynamiclimitErgodichypothesisFluctuation–dissipationtheoremPhasetransitionOrderparameterCriticalphenomenaUniversalityclassHeat capacityQuantum fieldtheoryGauge fieldtheoryGaugeredundancyGlobal physicalsymmetryLocalityprincipleQuantum fieldAbelian gaugetheoryCanonical fieldquantizationGauge fieldLocal gaugeinvarianceMatter fieldMicrocausalityNoethertheoremNon-Abeliangauge theoryPath-integralformulationQuantum fieldoperatorScalar fieldSpinor fieldStandard Modelgauge groupVector field inphysicsYang–MillstheoryBosonicquantum fieldEffective fieldtheoryElectroweaktheoryFermionicquantum fieldFree quantumfieldGauge fixingGaugeinteractionNoethercurrentOperator-valueddistributionQuantumchromodynamicsScalarself-interactionSpontaneoussymmetrybreakingStandard ModelLagrangianVacuum stateYukawainteractionBRST symmetryConservedchargeFaddeev–Popovghost fieldGluon gaugefieldHiggs doubletfieldInteractingquantum fieldPerturbativequantum fieldtheoryRegularizationRenormalizationgroupStandard Modelchiral fermionmultipletStandard Modelfermion fieldWeak-hyperchargegauge fieldWeak-isospingauge fieldsAsymptoticfreedomBrout–Englert–HiggsmechanismCorrelationfunctionElectroweaksymmetrybreakingGluonself-interactionHiggs vacuumexpectation valueLeft-handedlepton doubletfieldLeft-handed quarkdoublet fieldLepton fieldOne-particlestateQuark fieldQuark–gluoninteractionRenormalizationRight-handedcharged-leptonfieldRight-handeddown-type quarkfieldRight-handedup-type quarkfieldRunningcoupling𝑍 fieldCharged 𝑊fieldsElectroweakgauge-fieldmixingHiggs fieldLattice QCDMultiparticlestatePhoton fieldPropagatorChargeconjugationFeynmandiagramQuantumelectrodynamics𝑆-matrixScatteringamplitudeWilsonianeffective actionLeft-handedfermion fieldPhoton–fermioninteractionRight-handedfermion fieldStandard Modeleffective fieldtheoryFermi theory ofweak interactionsLow-energyQCDFour-fermioninteractionChiralperturbationtheoryCPT theoremElectroweakgauge-bosonself-interactionGauge-anomalycancellationHiggs–gaugeinteractionQuantumanomalySpin–statisticstheoremGauge-covariantderivativeGauge fieldstrengthGoldstonetheoremNambu–GoldstonemodeWould-beGoldstone modeLongitudinalmassive-gauge-bosonmodeLow-energyeffective fieldtheory below theelectroweak scale(LEFT)Approximatechiral symmetryof QCDSpontaneouschiral-symmetrybreaking in QCDQuarkcondensatePseudo-Nambu–GoldstonemodeYang–Millsmass gapElectronanomalous-magnetic-momentmeasurementsCasimir-forcemeasurementsWard–TakahashiidentityStronginteractionWeak mixingangleBaryon numberChiralityCKM matrixColor chargeElectric chargeElectromagneticinteractionLepton numberParticle massPMNS matrixStandard Model ofparticle physicsWeakhyperchargeWeakinteractionWeak isospinAntiparticleBosonCharged leptonCharged-currentweak interactionElementaryparticleFermionFermiongenerationFlavorGauge bosonHelicityLeptonNeutral-currentweak interactionNeutrino massNeutrinomixingParticle or fieldpolarizationQuarkQuark flavormixingAntiquarkBottom quarkCharm quarkColorconfinementDown quarkElectronFirst fermiongenerationGluonHiggs bosonMuonNeutrinoNeutrinooscillationPhotonSecond fermiongenerationStrange quarkTau leptonThird fermiongenerationTop quarkUp quark𝑊 boson𝑍 bosonElectronantineutrinoElectronneutrinoHadronizationMuon neutrinoPositronTau neutrinoColor-singletstateCompositeparticleConstituent-quarkmodelSea-quarkdegrees offreedomValence-quarkcontentHadronBaryonMesonIsospinAntineutrinoNeutrino flavorstateNeutrino masseigenstateMuonantineutrinoTauantineutrinoThomsoncathode-rayexperimentsMillikan oil-dropexperimentPositron discoveryin cloud-chambertracksMuon discoveryin cosmic raysCowan–Reinesreactor-neutrinoexperimentWu parityexperimentGoldhaberneutrino-helicityexperimentBrookhavenmuon-neutrinoexperimentKaon CP-violationexperimentSolar-neutrinodeficitSLACdeep-inelasticscatteringexperimentsGargamelleneutral-currentdiscovery𝐽/𝜓 discovery andthe NovemberRevolutionTau-leptondiscoveryUpsilon andbottom-quarkdiscoveryPETRA three-jetgluon evidenceUA1 and UA2discovery of the𝑊 and 𝑍 bosonsLEP precisionelectroweakmeasurementsTop-quarkdiscovery at theTevatronSuper-Kamiokandeatmospheric-neutrinoresultSNO solar-neutrinoflavor-changemeasurementATLAS and CMSHiggs-bosondiscoveryCP violationResidual stronginteractionNuclear effectivefield theoryNucleonPionNeutronNuclear forceNucleon–nucleoninteractionProtonAntineutronAntiprotonOne-pionexchangeThree-nucleonforceNuclear CoulombinteractionNuclearpotentialNuclearmany-bodysystemAtomic nucleusAlpha particleDeuteronMass number 𝐴Neutronnumber 𝑁Nuclear spinNuclear stateProton number𝑍Liquid-dropmodelNuclear bindingenergyNuclear energylevelNuclearmean-field theoryNuclear shellmodelNuclideIsotoneIsotopeNuclear isobarNuclear isomerNuclear massdefectRadioactivedecayAlpha decayBeta decayGamma decayBeta-minusdecayBeta-plusdecayElectroncaptureNuclear fissiontwo light nucleiin a fusionchannelNuclear fusionGeiger–Marsdengold-foilexperimentAstonmass-spectrographmeasurementsContinuousbeta-spectrumproblemChadwick neutronexperimentPion discovery innuclear emulsionsNuclearmagic-numbersystematicsRutherfordproton-transmutationexperimentNeutroncaptureNonrelativisticQEDAtomicHamiltonianElectromagneticatomic bindingElectron–electronCoulombinteractionElectron–nucleusCoulombinteractionNonrelativisticCoulombHamiltonianCenter-of-massseparationRelativisticatomic structureDirac–CoulombHamiltonianInfinite-nuclear-massapproximationReduced-masstreatmentAtomic QEDcorrectionsBreitinteractionNuclear recoilcorrectionAtomBound-electronself-energyOne-electronatomic systemVacuumpolarizationDarwin termElectronicscreeningExchangeinteractionHydrogen atomHydrogen-likeionMany-electronatomOrbitalangular-momentumquantum number 𝑙Principal quantumnumber 𝑛Relativistickinetic-energycorrectionSpin–orbitcouplingAtomic orbitalAtomic stateCentral-fieldapproximationConfiguration-statefunctionElectron shellFinite nuclear-sizeeffectIndependent-particlemodelMagneticquantum number𝑚Rutherfordnuclear atommodelSpin-projectionquantum number𝑚ₛAtomic energylevelBohr modelDensity-functionaltheoryElectroncorrelationElectronsubshellHartree methodjj couplingLS couplingRydbergformulaTotalangular-momentumquantum number 𝐽Atomic finestructureAtomicselection ruleAtomic termsymbolAtomic hyperfinestructureAtomicionizationAtomicspectrumAtomictransitionLamb shiftAtomicabsorptionAtomic isotopeshiftElectric-dipoletransitionSpontaneousemissionStark effectStimulatedemissionZeeman effectBalmerhydrogen-spectrumobservationsPerrinBrownian-motionexperimentsMoseley X-rayspectroscopyFranck–HertzexperimentLamb–RetherfordexperimentProton-radiuspuzzlePhotoionizationCondensed-matterphysicsQuantummany-bodysystemCollectiveexcitationQuasiparticleElectroniccondensed-mattersystemCrystallinesolidCrystal latticemodelPeriodic-electronmodelMagnetic orderSuperconductivityCooper pairReciprocallatticeLatticevibrationBloch theoremTight-bindingmodelNearly-free-electronmodelFerromagnetismConventionalsuperconductivityHubbard modelFermi-liquidtheoryPhononBloch stateElectronic bandstructureIsing modelBCS theoryFermi surfaceBand metalBand insulatorSemiconductorTwo-dimensionalelectron gasQuantum HalleffectMeasurementresultMeasurementuncertaintyCoulomb’storsion-balancemeasurementsMatter inchemistryChemicalsubstancePure substanceChemicalmixtureChemicalspeciesAmount ofsubstanceMoleMolar massChemicalcompoundChemicalformulaEmpiricalformulaMolecularformulaMass conservationin chemicalreactionsLaw of definiteproportionsLaw of multipleproportionsStoichiometryIonAnionCationMoleculeChemicalequationLavoisier’squantitativecombustionprogramProust’scompound-compositionmeasurementsLimitingreactantPeriodic lawPeriodic tableChemicalelementPeriodic-tablegroupPeriodic-tableperiodValenceelectronEffectivenuclear chargeChemicalvalenceElectronegativityElectron affinityAtomic-radiustrendOxidation statePeriodic trendMendeleev’speriodicpredictionsGallium discoveryand periodicprediction testElectronconfigurationIonizationenergyPeriodic-tableblockMolecularstructureChemical bondValence-bondtheoryMolecular-orbitaltheoryLewis structureFormal chargeResonance inchemicalstructureVSEPR modelOrbitalhybridizationBond orderCovalent bondIonic bondingHydrogen bondIntermolecularinteractionMoleculargeometryMolecularsymmetryMoleculardipole momentMolecularconformationMoleculargraphSigma bondPi bondQuantumchemistryBorn–OppenheimerapproximationElectronic-structurecalculationAb initio quantumchemistryHartree–FockmethodPotential-energysurfaceConfigurationinteractionCoupled-clustermethodMolecularvibrationMolecularrotationMolecularspectroscopyRotationalspectroscopyVibrationalspectroscopyInfraredspectroscopyRamanspectroscopyUltraviolet–visiblespectroscopyNuclear magneticresonancespectroscopyBeer–LambertlawRaman’sinelastic-scatteringobservationsBloch–Purcellnuclear-inductionexperimentsBasis setChemicalthermodynamicsChemicalstandard stateEnthalpyChemicalpotentialGibbs energyReactionenthalpyCalorimetryHess’s lawLaw of massactionChemicalequilibriumEquilibriumconstantReactionquotientLe Chatelier’sprincipleGibbs phaseruleChemical phasediagramGuldberg–Waagereaction studiesHess’sthermochemicalmeasurementsStandard reactionGibbs energySolutionSolventSoluteChemicalconcentrationChemicalactivityActivitycoefficientIdeal solutionRaoult’s lawHenry’s lawColligativepropertyOsmosisOsmoticpressureElectrolytesolutionElectrolyticdissociationBrønsted–Lowryacid–basechemistry𝑝𝐻Buffer solutionSolubilityequilibriumAcid–baseequilibriumAcid dissociationconstantLewis acid–basechemistryAmphoterismChemicalinterfaceSurfacechemistrySurface tensionAdsorptionAdsorptionisothermLangmuiradsorption modelColloidSurfactantMicelleLangmuir’sadsorption andmonolayerexperimentsArrhenius’selectrolyte-conductivitystudiesvan ’t Hoffosmotic-pressurecomparisonsIonic strengthChemicalreactionChemicalkineticsReaction rateRate lawElementaryreactionReactionmechanismReactioncoordinateTransition stateActivationenergySteady-stateapproximationArrheniusequationCollision theoryTransition-statetheoryCatalysisHomogeneouscatalysisHeterogeneouscatalysisPhotochemistryArrheniustemperature–ratecomparisonsZewail’sfemtochemistryexperimentsRate-determiningstepInorganiccompoundIonic compoundLigandCoordinationtheoryCoordinationcomplexCoordinationnumberChelationMetal–ligandbondingCrystal-fieldtheoryLigand-fieldtheoryTransition-metalchemistryOrganometalliccompoundOxidativeadditionReductiveeliminationLigandsubstitutionBioinorganicchemistryWerner’scoordination-isomerstudiesOrganiccompoundOrganicsynthesisFunctionalgroupCarbonyl groupCarbonylcompoundHydrocarbonAromaticityHeterocycleConstitutionalisomerStereochemistryMolecularchiralityEnantiomerNucleophileElectrophileReactionintermediateSubstitutionreactionEliminationreactionAdditionreactionPericyclicreactionRetrosyntheticanalysisWöhler’s ureasynthesisPasteur’s tartrateresolutionAnalyticalchemistryQualitativechemical analysisQuantitativechemical analysisChemicalmeasurementChemicalsamplingChemicalreferencematerialMetrologicaltraceability inchemistryCalibrationcurveChemicalmeasurementuncertaintyDetection limitSeparationscienceChromatographyGaschromatographyLiquidchromatographyMassspectrometrySpectrophotometryTitrationX-raycrystallographyStandard-additionmethodMass-spectrometricisotope-ratiomeasurementTsvet’s pigmentchromatographyexperimentsBragg X-raydiffractionexperimentsElectrochemistryRedox reactionElectrolyteElectrodeElectrochemicalcellElectrodepotentialStandardelectrodepotentialNernstequationGalvanic cellElectrolytic cellElectrolysisFaraday’s lawsof electrolysisElectrochemicaldouble layerElectrodeoverpotentialCyclicvoltammetryElectrodekineticsButler–VolmerequationBatteryFuel cellElectrochemicalcorrosionVoltaic-pileexperimentsFaraday’selectrolysisexperimentsNernstconcentration-cellmeasurementsRadiochemistryRadionuclideRadiationchemistryIsotope tracerIsotope-dilutionanalysisNeutron-activationanalysisRadiometricdatingRadioactivedecay chainRadiocarbondatingRadiopharmaceuticalActinideseparationchemistryNuclear-fuel-cyclechemistryCurieradium-separationmeasurementsSoddy’s isotopeand displacementevidenceLibby’sradiocarbonvalidationmeasurements