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Atomic Hamiltonian

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Summary

The Hamiltonian describing nuclear and electronic kinetic energy plus electromagnetic interactions, with relativistic, finite-size, recoil, and QED refinements as required.

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Concept sources

Incoming relations (arrows to this concept)

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Nuclear recoil correctionAtomic Hamiltonian

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Nuclear recoil and mass-polarization terms are finite-nuclear-mass components of precision atomic Hamiltonians.

How to interpret this relation type

The source supplies a substantive formal ingredient, dynamical sector, law, field content, or mechanism of the target theoretical framework.

Relation sources

Quantum electrodynamicsAtomic Hamiltonian

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Atomic Hamiltonians are low-energy bound-state descriptions matched to QED, with nuclear structure and weak/gravitational effects added when relevant.

How to interpret this relation type

The target retains the degrees of freedom and interactions relevant below a stated scale or within a stated regime, while higher-energy or unresolved degrees of freedom from the source are integrated out, coarse-grained, or encoded in effective couplings.

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Outgoing relations (arrows from this concept)

Each relation below starts at this concept.

Atomic HamiltonianAtom

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

An atomic Hamiltonian describes the internal dynamics and energy spectrum of an atom within its stated effective and approximation regime.

How to interpret this relation type

A theory, law, or interaction describes the behavior of the target within a stated regime. The edge detail must state important limits or qualifications.

Relation sources

Atomic HamiltonianInfinite-nuclear-mass approximation

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Fixing the nucleus is controlled by small electron-to-nuclear mass ratios, but precision work restores recoil and mass-polarization terms.

How to interpret this relation type

The target is recovered from the source either in a stated mathematical or asymptotic limit, or through a quantitatively controlled approximation with identified small parameters or omitted terms. The edge label and detail must state which case applies and its regime of validity.

Relation sources

Atomic HamiltonianNonrelativistic Coulomb Hamiltonian

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

The Coulomb Hamiltonian is the leading nonrelativistic, instantaneous-interaction model when transverse-photon, relativistic, radiative, and finite-size effects are below the required accuracy. It may retain finite nuclear masses and recoil through the nuclear kinetic terms and reduced-mass separation.

How to interpret this relation type

The target is recovered from the source either in a stated mathematical or asymptotic limit, or through a quantitatively controlled approximation with identified small parameters or omitted terms. The edge label and detail must state which case applies and its regime of validity.

Relation sources

Atomic HamiltonianRelativistic atomic structure

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Relativistic atomic structure replaces or augments the nonrelativistic Hamiltonian with Dirac-based and QED-matched descriptions when ZαZ\alpha or required precision makes relativistic effects important.

How to interpret this relation type

A more specific theory, model, entity class, or regime is obtained by restricting or extending the scope of a broader framework.

Relation sources