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Statistical partition function

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Summary

The normalization sum, trace, or integral over statistical weights. In equilibrium ensembles its logarithm generates free energies and derivatives that yield expectation values and response coefficients.

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Canonical ensembleStatistical partition function

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

The canonical partition function is the trace, sum, or phase-space integral of Boltzmann weights and normalizes the canonical distribution.

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The target represents a state, property, observable, or state-dependent description associated with the source system or theory.

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Statistical partition functionHelmholtz free energy

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

For a canonical equilibrium system, the partition function canonically determines the Helmholtz free energy by F=kBTlnZF=-k_{\mathrm B}T\ln Z.

How to interpret this relation type

Apply a standard functorial or canonical construction whose output is not merely a reduct of the input and is not generally an equivalent presentation of the same object.

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