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A mathematical relation between reaction rate and state variables or species activities, determined by mechanism or experiment rather than overall stoichiometry alone.
wp-chem-chemical-kineticsopenstax-chemistry-2edoe-catalystsEach relation below ends at this concept.
This is an authored directed relation from the source endpoint to the target endpoint.
A rate law is an empirical or mechanism-derived model of chemical kinetics valid over stated composition, temperature, pressure, phase, and transport regimes.
The target is a model, idealization, restricted ansatz, approximation scheme, phenomenological fit, or historical representation used for the source system or theory. It need not have a universal small error parameter and is not thereby a controlled limit or effective theory. The edge label and detail must identify the precise status.
wp-chem-chemical-kineticsopenstax-chemistry-2edoe-catalystsThis is an authored directed relation from the source endpoint to the target endpoint.
For simple gas reactions, collision theory estimates rate coefficients from collision and reaction probabilities.
The target is a model, idealization, restricted ansatz, approximation scheme, phenomenological fit, or historical representation used for the source system or theory. It need not have a universal small error parameter and is not thereby a controlled limit or effective theory. The edge label and detail must identify the precise status.
wp-chem-chemical-kineticsopenstax-chemistry-2edoe-catalystsThis is an authored directed relation from the source endpoint to the target endpoint.
Concentrations supply commonly used kinetic variables, while activities, surface coverages, particle numbers, or spatial fields can be required outside dilute well-mixed regimes.
The source supplies a substantive formal ingredient, dynamical sector, law, field content, or mechanism of the target theoretical framework.
wp-chem-solutionopenstax-chemistry-2eiupac-solubility-dataiupac-gold-bookThis is an authored directed relation from the source endpoint to the target endpoint.
Mass-action kinetics gives elementary-step rates proportional to reactant activities or concentrations under its regime; empirical overall reaction orders need not equal stoichiometric coefficients.
A theory, law, or interaction describes the behavior of the target within a stated regime. The edge detail must state important limits or qualifications.
wp-chem-chemical-thermodynamicsopenstax-chemistry-2eiupac-green-booknist-chemistry-webbookThis is an authored directed relation from the source endpoint to the target endpoint.
Rate control can determine an approximate rate law only with the accompanying mechanistic assumptions; a single slow-step slogan is insufficient when steps are coupled or partially reversible.
A theory, law, or interaction describes the behavior of the target within a stated regime. The edge detail must state important limits or qualifications.
wp-chem-chemical-kineticsopenstax-chemistry-2edoe-catalystsThis is an authored directed relation from the source endpoint to the target endpoint.
A proposed mechanism yields a rate law only after approximations, conservation equations, and initial conditions are stated.
A theory, law, or interaction describes the behavior of the target within a stated regime. The edge detail must state important limits or qualifications.
wp-chem-chemical-kineticsopenstax-chemistry-2edoe-catalystsThis is an authored directed relation from the source endpoint to the target endpoint.
Transition-state theory connects an activated-complex partition function and free-energy barrier to a rate coefficient.
The target is a model, idealization, restricted ansatz, approximation scheme, phenomenological fit, or historical representation used for the source system or theory. It need not have a universal small error parameter and is not thereby a controlled limit or effective theory. The edge label and detail must identify the precise status.
wp-chem-chemical-kineticsopenstax-chemistry-2edoe-catalystsEach relation below starts at this concept.
No direct relations are authored in this direction.