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Mass spectrometry

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Summary

Production, separation, and detection of gas-phase ions according to mass-to-charge ratio, often with structural inference from fragmentation and exact mass.

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Incoming relations (arrows to this concept)

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Analytical chemistryMass spectrometry

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Mass spectrometry supports elemental, molecular, isotopic, and structural analysis through ion measurements.

How to interpret this relation type

The target is a member or subtype of the broader source class.

Relation sources

Isotope-dilution analysisMass spectrometry

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Mass spectrometry tests an isotope-dilution amount estimate through measured isotope ratios after spike equilibration, blank correction, fractionation control, and a stated measurement equation.

How to interpret this relation type

The source theory, law, entity, prediction, or structural claim is directly tested, supported, constrained, or established by the target experiment or observation. Experimental support is not final logical proof; the edge detail states exactly what was measured.

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Each relation below starts at this concept.

Mass spectrometryAston mass-spectrograph measurements

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Aston’s positive-ray mass spectrograph demonstrated chemically consequential isotopic mass patterns and the analytical power of mass-to-charge separation.

How to interpret this relation type

The source theory, law, entity, prediction, or structural claim is directly tested, supported, constrained, or established by the target experiment or observation. Experimental support is not final logical proof; the edge detail states exactly what was measured.

Relation sources

Mass spectrometryIon

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

A mass-spectrometric workflow ionizes analyte species before separating and detecting the resulting gas-phase ions; the ionization method can fragment, adduct, or otherwise alter what is observed.

How to interpret this relation type

A physical process transforms the source into, or produces, the target under the conditions stated in the edge detail.

Relation sources

Mass spectrometryMass-spectrometric isotope-ratio measurement

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Isotope-ratio mass spectrometry specializes mass spectrometry to calibrated relative ion-signal measurements, where mass discrimination, isobaric overlap, chemical preparation, and reference materials limit the inferred isotope ratio.

How to interpret this relation type

A more specific theory, model, entity class, or regime is obtained by restricting or extending the scope of a broader framework.

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