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Nearly-free-electron model

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Summary

A perturbative model of electrons moving in a weak lattice-periodic potential. Bragg mixing opens gaps near degeneracies, while states far from those surfaces remain close to free-electron states.

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Periodic-electron modelNearly-free-electron model

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

When the periodic potential is weak relative to the free-electron kinetic scale, perturbation theory recovers nearly free dispersion away from Bragg degeneracies and controlled gap opening after degenerate perturbation theory.

How to interpret this relation type

The target is recovered from the source either in a stated mathematical or asymptotic limit, or through a quantitatively controlled approximation with identified small parameters or omitted terms. The edge label and detail must state which case applies and its regime of validity.

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Nearly-free-electron modelElectronic band structure

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

The nearly-free approximation produces bands close to the free-electron parabola, with gaps opened where reciprocal-lattice scattering mixes degenerate plane waves.

How to interpret this relation type

The target represents a state, property, observable, or state-dependent description associated with the source system or theory.

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