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Electrode overpotential

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Summary

The departure of an electrode potential from its equilibrium value required to sustain a specified current under kinetic and transport losses.

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Butler–Volmer equationElectrode overpotential

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

Under its stated assumptions, the equation relates activation overpotential to the net current through anodic and cathodic partial-current terms; measured overpotential can also include transport and resistive contributions outside that relation.

How to interpret this relation type

A theory, law, or interaction describes the behavior of the target within a stated regime. The edge detail must state important limits or qualifications.

Relation sources

ElectrodeElectrode overpotential

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This is an authored directed relation from the source endpoint to the target endpoint.

Authored explanation

An operating electrode has an overpotential relative to a defined equilibrium potential; charge transfer, mass transport, resistance, bubbles, area, and reference placement can all contribute.

How to interpret this relation type

The target represents a state, property, observable, or state-dependent description associated with the source system or theory.

Relation sources

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No direct relations are authored in this direction.